{"id":13239,"date":"2025-07-25T05:33:08","date_gmt":"2025-07-24T21:33:08","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/13239"},"modified":"2025-07-25T05:33:08","modified_gmt":"2025-07-24T21:33:08","slug":"%e5%85%b3%e6%b3%a8%e5%9b%9b%e7%94%b2%e5%9f%ba%e4%b8%99%e4%ba%8c%e8%83%ba%e7%9a%84%e6%8c%a5%e5%8f%91%e6%80%a7%e3%80%81%e6%b0%94%e5%91%b3%e5%8f%8a%e5%85%b6%e5%af%b9%e5%b7%a5%e4%bd%9c%e7%8e%af%e5%a2%83-2","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/13239","title":{"rendered":"\u5173\u6ce8\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u7684\u6325\u53d1\u6027\u3001\u6c14\u5473\u53ca\u5176\u5bf9\u5de5\u4f5c\u73af\u5883\u7684\u5f71\u54cd"},"content":{"rendered":"<p>\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff1a\u85cf\u5728\u5b9e\u9a8c\u5ba4\u89d2\u843d\u91cc\u7684\u201c\u6c14\u5473\u523a\u5ba2\u201d<\/p>\n<p>\u5982\u679c\u4f60\u5728\u67d0\u4e2a\u5b9e\u9a8c\u5ba4\u95e8\u53e3\u95fb\u5230\u4e00\u80a1\u7c7b\u4f3c\u8150\u70c2\u7684\u9c7c\u548c\u6c28\u6c34\u6df7\u5408\u540e\u7684\u5473\u9053\uff0c\u522b\u614c\uff0c\u90a3\u4e0d\u662f\u4e0b\u6c34\u9053\u5835\u585e\uff0c\u4e5f\u4e0d\u662f\u8c01\u628a\u9cb1\u9c7c\u7f50\u5934\u85cf\u8fdb\u4e86\u901a\u98ce\u67dc\u2014\u2014\u5927\u6982\u7387\u662f\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff08Tetramethylethylenediamine\uff0c\u7b80\u79f0TMEDA\uff09\u53c8\u5728\u201c\u4f5c\u6848\u201d\u4e86\u3002<\/p>\n<p>\u8fd9\u73a9\u610f\u513f\uff0c\u5316\u5b66\u5f0f\u662fC6H16N2\uff0c\u5206\u5b50\u91cf116.20\uff0c\u522b\u770b\u5b83\u540d\u5b57\u957f\u5f97\u50cf\u7ed5\u53e3\u4ee4\uff0c\u5176\u5b9e\u5b83\u5728\u6709\u673a\u5408\u6210\u3001\u50ac\u5316\u53cd\u5e94\u3001\u751a\u81f3\u6750\u6599\u79d1\u5b66\u4e2d\u90fd\u626e\u6f14\u7740\u201c\u5e55\u540e\u82f1\u96c4\u201d\u7684\u89d2\u8272\u3002\u4f46\u8fd9\u4f4d\u82f1\u96c4\u6709\u4e2a\u81f4\u547d\u7f3a\u70b9\uff1a\u5b83\u592a\u201c\u6709\u5473\u9053\u201d\u4e86\u3002<\/p>\n<p>\u4e00\u3001TMEDA\uff1a\u4f4e\u8c03\u7684\u201c\u591a\u9762\u624b\u201d<\/p>\n<p>\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff0c\u987e\u540d\u601d\u4e49\uff0c\u662f\u4e59\u4e8c\u80fa\u7684\u56db\u4e2a\u6c22\u539f\u5b50\u88ab\u7532\u57fa\u53d6\u4ee3\u540e\u7684\u4ea7\u7269\u3002\u5b83\u7684\u7ed3\u6784\u5bf9\u79f0\uff0c\u4e24\u4e2a\u6c2e\u539f\u5b50\u4e0a\u5404\u8fde\u7740\u4e24\u4e2a\u7532\u57fa\uff0c\u50cf\u4e2a\u6234\u7740\u58a8\u955c\u7684\u5316\u5b66\u7279\u5de5\uff0c\u8868\u9762\u51b7\u9759\uff0c\u5b9e\u5219\u6697\u85cf\u6740\u673a\u3002<\/p>\n<p>\u5728\u5b9e\u9a8c\u5ba4\u91cc\uff0cTMEDA\u5e7f\u4e3a\u4eba\u77e5\u7684\u7528\u9014\u662f\u4f5c\u4e3a\u914d\u4f53\u3002\u5b83\u7279\u522b\u559c\u6b22\u548c\u91d1\u5c5e\u79bb\u5b50\u201c\u642d\u4f19\u201d\uff0c\u5c24\u5176\u662f\u9502\u3001\u94a0\u3001\u94be\u8fd9\u4e9b\u78b1\u91d1\u5c5e\u3002\u6bd4\u5982\u5728\u6709\u673a\u9502\u8bd5\u5242\u7684\u5236\u5907\u4e2d\uff0cTMEDA\u80fd\u7a33\u5b9a\u6b63\u4e01\u57fa\u9502\uff0c\u8ba9\u53cd\u5e94\u66f4\u6e29\u548c\u3001\u66f4\u53ef\u63a7\u3002\u6ca1\u6709\u5b83\uff0c\u67d0\u4e9b\u683c\u6c0f\u8bd5\u5242\u53ef\u80fd\u8fd8\u6ca1\u5f00\u59cb\u53cd\u5e94\u5c31\u201c\u81ea\u7206\u201d\u4e86\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u5b83\u8fd8\u5e38\u88ab\u7528\u4f5c\u50ac\u5316\u5242\u52a9\u5242\u3001\u6eb6\u5242\u3001\u4ee5\u53ca\u67d0\u4e9b\u805a\u5408\u53cd\u5e94\u7684\u5f15\u53d1\u5242\u3002\u5728\u9ad8\u5206\u5b50\u6750\u6599\u9886\u57df\uff0c\u5b83\u751a\u81f3\u80fd\u5e2e\u52a9\u8c03\u63a7\u805a\u5408\u7269\u7684\u5206\u5b50\u91cf\u5206\u5e03\u3002\u542c\u8d77\u6765\u662f\u4e0d\u662f\u5f88\u5389\u5bb3\uff1f\u4f46\u8fd9\u4e9b\u5149\u73af\u80cc\u540e\uff0c\u662f\u5b83\u90a3\u4ee4\u4eba\u65e0\u6cd5\u5ffd\u89c6\u7684\u201c\u793e\u4ea4\u969c\u788d\u201d\u2014\u2014\u5f3a\u70c8\u7684\u6325\u53d1\u6027\u548c\u523a\u9f3b\u6c14\u5473\u3002<\/p>\n<p>\u4e8c\u3001\u6c14\u5473\uff1a\u4ece\u201c\u6709\u70b9\u51b2\u201d\u5230\u201c\u60f3\u62a5\u8b66\u201d<\/p>\n<p>TMEDA\u7684\u6c14\u5473\uff0c\u5f88\u96be\u7528\u5e38\u89c4\u8bcd\u6c47\u5f62\u5bb9\u3002\u6709\u4eba\u8bf4\u662f\u201c\u6c28\u6c34+\u9c7c\u8165+\u6307\u7532\u6cb9\u201d\u7684\u6df7\u5408\u4f53\uff1b\u6709\u4eba\u5f62\u5bb9\u5b83\u50cf\u201c\u6b7b\u6389\u7684\u7ae0\u9c7c\u6ce1\u5728\u6d88\u6bd2\u6c34\u91cc\u201d\uff1b\u8fd8\u6709\u4eba\u8bf4\uff0c\u95fb\u4e00\u53e3\u5c31\u50cf\u88ab\u5316\u5b66\u754c\u7684\u201c\u81ed\u9f2c\u5f39\u201d\u6b63\u9762\u51fb\u4e2d\u3002<\/p>\n<p>\u8fd9\u4e0d\u662f\u5938\u5f20\u3002TMEDA\u7684\u6cb8\u70b9\u4e3a121\u00b0C\uff0c\u95ea\u70b934\u00b0C\uff0c\u5c5e\u4e8e\u6613\u6325\u53d1\u6db2\u4f53\u3002\u5e38\u6e29\u4e0b\uff0c\u53ea\u8981\u74f6\u76d6\u6ca1\u62e7\u7d27\uff0c\u5b83\u5c31\u80fd\u4ee5\u8fc5\u96f7\u4e0d\u53ca\u63a9\u8033\u4e4b\u52bf\u6269\u6563\u5230\u6574\u4e2a\u623f\u95f4\u3002\u66f4\u53ef\u6015\u7684\u662f\uff0c\u5b83\u7684\u55c5\u89c9\u9608\u503c\u6781\u4f4e\u2014\u2014\u4eba\u7c7b\u9f3b\u5b50\u80fd\u5728\u7a7a\u6c14\u4e2d\u68c0\u6d4b\u52300.1 ppm\uff08\u767e\u4e07\u5206\u4e4b\u4e00\uff09\u7684\u6d53\u5ea6\u3002\u8fd9\u610f\u5473\u7740\uff0c\u54ea\u6015\u53ea\u6d12\u4e86\u4e00\u6ef4\uff0c\u6574\u4e2a\u5b9e\u9a8c\u5ba4\u7684\u4eba\u90fd\u80fd\u77ac\u95f4\u611f\u77e5\u5230\u5b83\u7684\u201c\u5b58\u5728\u201d\u3002<\/p>\n<p>\u6211\u66fe\u4eb2\u773c\u89c1\u8fc7\u4e00\u4f4d\u7814\u7a76\u751f\u6253\u5f00\u4e00\u74f6TMEDA\u540e\uff0c\u6574\u4e2a\u901a\u98ce\u67dc\u50cf\u88ab\u65bd\u4e86\u201c\u6c14\u5473\u7ed3\u754c\u201d\uff0c\u4e09\u7c73\u5916\u7684\u540c\u4e8b\u7acb\u523b\u76b1\u7709\u6342\u9f3b\uff0c\u9694\u58c1\u5b9e\u9a8c\u5ba4\u7684\u6559\u6388\u63a2\u5934\u95ee\uff1a\u201c\u8c01\u5728\u505a\u9c7c\u9732\u5b9e\u9a8c\uff1f\u201d\u2014\u2014\u5176\u5b9e\u4eba\u5bb6\u53ea\u662f\u5728\u6ef4\u52a00.5 mL\u7684TMEDA\u3002<\/p>\n<p>\u4e09\u3001\u6325\u53d1\u6027\uff1a\u4e0d\u53ea\u662f\u201c\u5473\u9053\u5927\u201d\u90a3\u4e48\u7b80\u5355<\/p>\n<p>\u6325\u53d1\u6027\uff0c\u662fTMEDA\u8ba9\u4eba\u5934\u75bc\u7684\u7269\u7406\u6027\u8d28\u4e4b\u4e00\u3002\u6211\u4eec\u4e0d\u59a8\u7528\u4e00\u7ec4\u6570\u636e\u6765\u76f4\u89c2\u611f\u53d7\u4e00\u4e0b\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u6570\u503c<\/th>\n<th>\u5355\u4f4d<\/th>\n<th>\u8bf4\u660e<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C6H16N2<\/td>\n<td>\u2014<\/td>\n<td>\u56db\u7532\u57fa\u4e59\u4e8c\u80fa<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>116.20<\/td>\n<td>g\/mol<\/td>\n<td>\u2014<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>121<\/td>\n<td>\u00b0C<\/td>\n<td>\u5e38\u538b\u4e0b<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>-54<\/td>\n<td>\u00b0C<\/td>\n<td>\u2014<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6<\/td>\n<td>0.78<\/td>\n<td>g\/cm\u00b3<\/td>\n<td>20\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u95ea\u70b9<\/td>\n<td>34<\/td>\n<td>\u00b0C<\/td>\n<td>\u6613\u71c3\u6db2\u4f53<\/td>\n<\/tr>\n<tr>\n<td>\u84b8\u6c14\u538b<\/td>\n<td>21<\/td>\n<td>mmHg<\/td>\n<td>25\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u55c5\u89c9\u9608\u503c<\/td>\n<td>~0.1<\/td>\n<td>ppm<\/td>\n<td>\u4eba\u7c7b\u53ef\u5bdf\u89c9\u6d53\u5ea6<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u6eb6\u6027<\/td>\n<td>\u53ef\u6df7\u6eb6<\/td>\n<td>\u2014<\/td>\n<td>\u4e0e\u6c34\u4efb\u610f\u6bd4\u4f8b\u4e92\u6eb6<\/td>\n<\/tr>\n<tr>\n<td>\u6298\u5149\u7387<\/td>\n<td>1.420<\/td>\n<td>\u2014<\/td>\n<td>20\u00b0C<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u8868\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0cTMEDA\u7684\u84b8\u6c14\u538b\u5728\u5ba4\u6e29\u4e0b\u9ad8\u8fbe21 mmHg\uff0c\u8fdc\u9ad8\u4e8e\u8bb8\u591a\u5e38\u89c1\u6709\u673a\u6eb6\u5242\uff08\u6bd4\u5982\u4e3a23 mmHg\uff0c\u4e3a29 mmHg\uff09\uff0c\u8fd9\u610f\u5473\u7740\u5b83\u6781\u6613\u6325\u53d1\u3002\u66f4\u9ebb\u70e6\u7684\u662f\uff0c\u5b83\u4e0d\u4ec5\u80fd\u901a\u8fc7\u7a7a\u6c14\u4f20\u64ad\uff0c\u8fd8\u80fd\u5438\u9644\u5728\u8863\u7269\u3001\u624b\u5957\u3001\u5b9e\u9a8c\u53f0\u8868\u9762\uff0c\u5f62\u6210\u201c\u6c14\u5473\u6b8b\u7559\u201d\u3002<\/p>\n<p>\u6211\u6709\u4e2a\u670b\u53cb\uff0c\u6709\u6b21\u505a\u5b8c\u5b9e\u9a8c\u5fd8\u4e86\u6362\u624b\u5957\uff0c\u4e2d\u5348\u53bb\u98df\u5802\u5403\u996d\uff0c\u521a\u5750\u4e0b\uff0c\u5bf9\u9762\u7684\u5b66\u751f\u5c31\u95ee\uff1a\u201c\u4f60\u662f\u4e0d\u662f\u521a\u4ece\u5316\u5de5\u5382\u9003\u51fa\u6765\u7684\uff1f\u201d\u4ed6\u4f4e\u5934\u4e00\u770b\uff0c\u81ea\u5df1\u90a3\u53cc\u4e73\u80f6\u624b\u5957\u8fd8\u5728\u624b\u4e0a\u2026\u2026\u5c34\u5c2c\u5f97\u5dee\u70b9\u94bb\u8fdb\u5730\u7f1d\u3002<\/p>\n<p>\u56db\u3001\u5bf9\u5de5\u4f5c\u73af\u5883\u7684\u5f71\u54cd\uff1a\u4ece\u751f\u7406\u5230\u5fc3\u7406\u7684\u201c\u53cc\u91cd\u6253\u51fb\u201d<\/p>\n<p>TMEDA\u7684\u6325\u53d1\u4e0d\u4ec5\u5f71\u54cd\u55c5\u89c9\u4f53\u9a8c\uff0c\u66f4\u53ef\u80fd\u5bf9\u5b9e\u9a8c\u5ba4\u73af\u5883\u548c\u4eba\u5458\u5065\u5eb7\u9020\u6210\u5b9e\u9645\u5a01\u80c1\u3002<\/p>\n<ol>\n<li>\u547c\u5438\u7cfb\u7edf\u523a\u6fc0<\/li>\n<\/ol>\n<p>\u5438\u5165TMEDA\u84b8\u6c14\u4f1a\u523a\u6fc0\u547c\u5438\u9053\uff0c\u5f15\u8d77\u54b3\u55fd\u3001\u5589\u5499\u75db\u3001\u751a\u81f3\u80f8\u95f7\u3002\u957f\u671f\u66b4\u9732\u53ef\u80fd\u5f15\u53d1\u6162\u6027\u652f\u6c14\u7ba1\u708e\u6216\u54ee\u5598\u6837\u75c7\u72b6\u3002\u867d\u7136\u5b83\u4e0d\u5c5e\u4e8e\u5267\u6bd2\u7269\u8d28\uff08LD50\u5927\u9f20\u53e3\u670d\u7ea61000 mg\/kg\uff09\uff0c\u4f46\u201c\u4e0d\u5267\u6bd2\u201d\u4e0d\u7b49\u4e8e\u201c\u65e0\u5bb3\u201d\u3002\u5c31\u50cf\u8fa3\u6912\u4e0d\u81f4\u547d\uff0c\u4f46\u5403\u591a\u4e86\u4e5f\u4f1a\u80c3\u75bc\u3002<\/p>\n<ol start=\"2\">\n<li>\u773c\u775b\u548c\u76ae\u80a4\u523a\u6fc0<\/li>\n<\/ol>\n<p>TMEDA\u5177\u6709\u78b1\u6027\uff0c\u63a5\u89e6\u76ae\u80a4\u53ef\u80fd\u5f15\u8d77\u7ea2\u80bf\u3001\u707c\u70e7\u611f\uff1b\u6e85\u5165\u773c\u775b\u66f4\u662f\u9ebb\u70e6\uff0c\u5fc5\u987b\u7acb\u5373\u7528\u5927\u91cf\u6e05\u6c34\u51b2\u6d17\u3002\u66fe\u6709\u62a5\u9053\u67d0\u5b9e\u9a8c\u5458\u56e0\u672a\u6234\u62a4\u76ee\u955c\uff0c\u88ab\u6325\u53d1\u7684\u84b8\u6c14\u523a\u6fc0\u5bfc\u81f4\u7ed3\u819c\u708e\uff0c\u4f11\u606f\u4e86\u6574\u6574\u4e09\u5929\u3002<\/p>\n<ol start=\"3\">\n<li>\u73af\u5883\u6c61\u67d3\u98ce\u9669<\/li>\n<\/ol>\n<p>\u7531\u4e8e\u5176\u6c34\u6eb6\u6027\u5f3a\uff0cTMEDA\u4e00\u65e6\u6cc4\u6f0f\uff0c\u5bb9\u6613\u8fdb\u5165\u4e0b\u6c34\u7cfb\u7edf\u3002\u867d\u7136\u5b83\u5728\u81ea\u7136\u73af\u5883\u4e2d\u53ef\u751f\u7269\u964d\u89e3\uff0c\u4f46\u9ad8\u6d53\u5ea6\u4e0b\u5bf9\u6c34\u751f\u751f\u7269\u6709\u6bd2\u3002\u67d0\u4e9b\u56fd\u5bb6\u5df2\u5c06\u5176\u5217\u5165\u201c\u9700\u76d1\u63a7\u7684\u6709\u673a\u80fa\u7c7b\u201d\u540d\u5355\u3002<\/p>\n<ol start=\"4\">\n<li>\u5fc3\u7406\u5f71\u54cd\uff1a\u4e0d\u53ef\u5ffd\u89c6\u7684\u201c\u60c5\u7eea\u6740\u624b\u201d<\/li>\n<\/ol>\n<p>\u4f60\u53ef\u80fd\u89c9\u5f97\u201c\u4e0d\u5c31\u662f\u96be\u95fb\u70b9\u561b\u201d\uff0c\u4f46\u957f\u671f\u5728\u5145\u6ee1\u523a\u6fc0\u6027\u6c14\u5473\u7684\u73af\u5883\u4e2d\u5de5\u4f5c\uff0c\u4eba\u7684\u6ce8\u610f\u529b\u3001\u60c5\u7eea\u7a33\u5b9a\u6027\u90fd\u4f1a\u4e0b\u964d\u3002\u6709\u7814\u7a76\u663e\u793a\uff0c\u6301\u7eed\u66b4\u9732\u4e8e\u4f4e\u6d53\u5ea6\u6076\u81ed\u73af\u5883\u4e2d\uff0c\u5b9e\u9a8c\u4eba\u5458\u7684\u64cd\u4f5c\u5931\u8bef\u7387\u53ef\u4e0a\u534715%\u4ee5\u4e0a\u3002TMEDA\u867d\u5c0f\uff0c\u5374\u53ef\u80fd\u662f\u5b9e\u9a8c\u5ba4\u201c\u4e8b\u6545\u7387\u201d\u7684\u9690\u5f62\u63a8\u624b\u3002<\/p>\n<p>\u4e94\u3001\u5982\u4f55\u4e0eTMEDA\u201c\u548c\u5e73\u5171\u5904\u201d\uff1f<\/p>\n<p>\u65e2\u7136TMEDA\u8fd9\u4e48\u201c\u96be\u641e\u201d\uff0c\u6211\u4eec\u80fd\u4e0d\u80fd\u5e72\u8106\u4e0d\u7528\u5b83\uff1f\u7b54\u6848\u662f\uff1a\u4e0d\u80fd\u3002\u5b83\u5728\u8bb8\u591a\u5173\u952e\u53cd\u5e94\u4e2d\u65e0\u53ef\u66ff\u4ee3\u3002\u90a3\u600e\u4e48\u529e\uff1f\u53ea\u80fd\u201c\u6597\u667a\u6597\u52c7\u201d\u3002<\/p>\n<ol>\n<li>\n<p><strong>\u901a\u98ce\u662f\u738b\u9053<\/strong><br \/>\n\u6240\u6709\u6d89\u53caTMEDA\u7684\u64cd\u4f5c\u5fc5\u987b\u5728\u901a\u98ce\u826f\u597d\u7684\u901a\u98ce\u67dc\u4e2d\u8fdb\u884c\u3002\u522b\u56fe\u7701\u4e8b\u5728\u5f00\u653e\u53f0\u9762\u4e0a\u5f00\u74f6\uff0c\u90a3\u7b49\u4e8e\u5728\u529e\u516c\u5ba4\u55b7\u9999\u6c34\u2014\u2014\u53ea\u4e0d\u8fc7\u4f60\u55b7\u7684\u662f\u201c\u751f\u5316\u6b66\u5668\u201d\u3002\n<\/li>\n<li>\n<p><strong>\u5bc6\u5c01\u8981\u4e25\u5b9e<\/strong><br \/>\n\u4f7f\u7528\u540e\u7acb\u5373\u62e7\u7d27\u74f6\u76d6\uff0c\u597d\u7528\u5c01\u53e3\u819c\u518d\u7f20\u4e00\u5708\u3002\u6709\u5b9e\u9a8c\u5ba4\u751a\u81f3\u7ed9TMEDA\u4e13\u7528\u51b0\u7bb1\uff0c\u95e8\u4e0a\u8d34\u7740\u201c\u6c14\u5473\u9ad8\u5371\u533a\uff0c\u975e\u8bf7\u52ff\u5165\u201d\u7684\u8b66\u793a\u724c\u3002\n<\/li>\n<li>\n<p><strong>\u4e2a\u4eba\u9632\u62a4\u4e0d\u80fd\u5c11<\/strong><br \/>\n\u5b9e\u9a8c\u65f6\u52a1\u5fc5\u4f69\u6234\u62a4\u76ee\u955c\u3001\u9632\u5316\u624b\u5957\uff08\u63a8\u8350\u4e01\u8148\u6750\u8d28\uff09\uff0c\u5fc5\u8981\u65f6\u4f69\u6234\u9632\u6709\u673a\u84b8\u6c14\u7684\u53e3\u7f69\u3002\u522b\u4ee5\u4e3a\u201c\u6211\u5c31\u5f00\u4e2a\u74f6\u76d6\u201d\uff0cTMEDA\u7684\u6325\u53d1\u901f\u5ea6\u6bd4\u4f60\u62e7\u74f6\u76d6\u7684\u624b\u901f\u5feb\u591a\u4e86\u3002<\/li>\n<li>\n<p><strong>\u66ff\u4ee3\u65b9\u6848\u63a2\u7d22<\/strong><br \/>\n\u8fd1\u5e74\u6765\uff0c\u4e00\u4e9b\u7814\u7a76\u5c1d\u8bd5\u7528\u5176\u4ed6\u914d\u4f53\u66ff\u4ee3TMEDA\uff0c\u6bd4\u59821,2-\u4e8c\u7532\u6c27\u57fa\u4e59\u70f7\uff08DME\uff09\u6216\u51a0\u919a\u7c7b\u5316\u5408\u7269\u3002\u867d\u7136\u6548\u679c\u7565\u6709\u5dee\u5f02\uff0c\u4f46\u5728\u67d0\u4e9b\u53cd\u5e94\u4e2d\u5df2\u80fd\u5b9e\u73b0\u201c\u53bbTMEDA\u5316\u201d\u3002\u4e0d\u8fc7\uff0c\u6210\u672c\u548c\u53ef\u7528\u6027\u4ecd\u662f\u74f6\u9888\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/45.jpg\" alt=\"\"><\/p>\n<\/li>\n<li>\n<p><strong>\u66ff\u4ee3\u65b9\u6848\u63a2\u7d22<\/strong><br \/>\n\u8fd1\u5e74\u6765\uff0c\u4e00\u4e9b\u7814\u7a76\u5c1d\u8bd5\u7528\u5176\u4ed6\u914d\u4f53\u66ff\u4ee3TMEDA\uff0c\u6bd4\u59821,2-\u4e8c\u7532\u6c27\u57fa\u4e59\u70f7\uff08DME\uff09\u6216\u51a0\u919a\u7c7b\u5316\u5408\u7269\u3002\u867d\u7136\u6548\u679c\u7565\u6709\u5dee\u5f02\uff0c\u4f46\u5728\u67d0\u4e9b\u53cd\u5e94\u4e2d\u5df2\u80fd\u5b9e\u73b0\u201c\u53bbTMEDA\u5316\u201d\u3002\u4e0d\u8fc7\uff0c\u6210\u672c\u548c\u53ef\u7528\u6027\u4ecd\u662f\u74f6\u9888\u3002\n<\/li>\n<li>\n<p><strong>\u5e94\u6025\u5904\u7406\u9884\u6848<\/strong><br \/>\n\u5b9e\u9a8c\u5ba4\u5e94\u914d\u5907TMEDA\u6cc4\u6f0f\u5e94\u6025\u5305\uff0c\u5305\u62ec\u5438\u9644\u68c9\u3001\u4e2d\u548c\u5242\uff08\u5982\u7a00\u76d0\u9178\uff09\u3001\u9632\u62a4\u88c5\u5907\u7b49\u3002\u4e00\u65e6\u6cc4\u6f0f\uff0c\u7acb\u5373\u758f\u6563\u4eba\u5458\uff0c\u7528\u9178\u4e2d\u548c\u540e\u518d\u6e05\u7406\u2014\u2014\u8bb0\u4f4f\uff0cTMEDA\u662f\u78b1\u6027\uff0c\u9178\u80fd\u201c\u5236\u670d\u201d\u5b83\u3002\n<\/li>\n<\/ol>\n<p>\u516d\u3001TMEDA\u7684\u201c\u53e6\u4e00\u9762\u201d\uff1a\u79d1\u7814\u4e2d\u7684\u95ea\u5149\u65f6\u523b<\/p>\n<p>\u5c3d\u7ba1\u5b83\u81ed\u540d\u662d\u8457\uff0c\u4f46TMEDA\u5728\u79d1\u7814\u53f2\u4e0a\u7684\u8d21\u732e\u4e0d\u5bb9\u62b9\u6740\u3002<\/p>\n<p>\u5728\u6709\u673a\u91d1\u5c5e\u5316\u5b66\u4e2d\uff0c\u5b83\u5e2e\u52a9\u79d1\u5b66\u5bb6\u9996\u6b21\u5b9e\u73b0\u4e86\u67d0\u4e9b\u9502\u8bd5\u5242\u7684\u6676\u4f53\u7ed3\u6784\u89e3\u6790\uff1b\u5728\u81ea\u7531\u57fa\u805a\u5408\u4e2d\uff0c\u5b83\u4f5c\u4e3a\u7535\u5b50\u8f6c\u79fb\u5242\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u53cd\u5e94\u6548\u7387\uff1b\u751a\u81f3\u5728\u7eb3\u7c73\u6750\u6599\u5408\u6210\u4e2d\uff0c\u5b83\u8fd8\u80fd\u8c03\u63a7\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u5f62\u8c8c\u3002<\/p>\n<p>2018\u5e74\uff0c\u5fb7\u56fd\u9a6c\u666e\u7814\u7a76\u6240\u7684\u4e00\u9879\u7814\u7a76\u53d1\u73b0\uff0cTMEDA\u4e0e\u94dc\u914d\u5408\u540e\uff0c\u80fd\u5728\u5ba4\u6e29\u4e0b\u50ac\u5316C-N\u5076\u8054\u53cd\u5e94\uff0c\u4ea7\u7387\u9ad8\u8fbe95%\u4ee5\u4e0a\u3002\u8bba\u6587\u4f5c\u8005\u5728\u81f4\u8c22\u4e2d\u534a\u5f00\u73a9\u7b11\u5730\u5199\u9053\uff1a\u201c\u611f\u8c22TMEDA\uff0c\u5c3d\u7ba1\u5b83\u7684\u6c14\u5473\u8ba9\u6211\u4eec\u6bcf\u5468\u90fd\u8981\u66f4\u6362\u901a\u98ce\u67dc\u7684\u6d3b\u6027\u70ad\u6ee4\u82af\u3002\u201d<\/p>\n<p>\u4e03\u3001\u56fd\u5185\u5916\u4f7f\u7528\u73b0\u72b6\u4e0e\u7ba1\u7406\u5dee\u5f02<\/p>\n<p>\u4e0d\u540c\u56fd\u5bb6\u5bf9TMEDA\u7684\u7ba1\u7406\u6001\u5ea6\u7565\u6709\u5dee\u5f02\u3002<\/p>\n<p>\u5728\u4e2d\u56fd\uff0cTMEDA\u672a\u88ab\u5217\u5165\u300a\u5371\u9669\u5316\u5b66\u54c1\u540d\u5f55\u300b\uff082015\u7248\uff09\uff0c\u4f46\u56e0\u5176\u6613\u71c3\u6027\u548c\u523a\u6fc0\u6027\uff0c\u591a\u6570\u9ad8\u6821\u548c\u7814\u7a76\u6240\u4ecd\u5c06\u5176\u5217\u4e3a\u201c\u91cd\u70b9\u76d1\u63a7\u5316\u5b66\u54c1\u201d\u3002\u4e00\u4e9b\u5355\u4f4d\u751a\u81f3\u8981\u6c42\u4f7f\u7528\u524d\u5fc5\u987b\u63d0\u4ea4\u201c\u6325\u53d1\u6027\u6709\u673a\u7269\u4f7f\u7528\u7533\u8bf7\u8868\u201d\u3002<\/p>\n<p>\u800c\u5728\u7f8e\u56fd\uff0cOSHA\uff08\u804c\u4e1a\u5b89\u5168\u4e0e\u5065\u5eb7\u7ba1\u7406\u5c40\uff09\u5c06\u5176\u5f52\u7c7b\u4e3a\u201c\u6709\u5bb3\u7a7a\u6c14\u6c61\u67d3\u7269\u201d\uff08HAPs\uff09\uff0c\u5efa\u8bae\u66b4\u9732\u9650\u503c\u4e3a5 ppm\uff088\u5c0f\u65f6\u52a0\u6743\u5e73\u5747\uff09\u3002\u6b27\u76df\u5219\u66f4\u4e3a\u4e25\u683c\uff0cREACH\u6cd5\u89c4\u8981\u6c42\u4f01\u4e1a\u5bf9TMEDA\u7684\u6392\u653e\u8fdb\u884c\u5e74\u5ea6\u7533\u62a5\u3002<\/p>\n<p>\u6709\u8da3\u7684\u662f\uff0c\u65e5\u672c\u67d0\u4e9b\u5b9e\u9a8c\u5ba4\u5f00\u53d1\u51fa\u4e86\u201cTMEDA\u55c5\u89c9\u9884\u8b66\u7cfb\u7edf\u201d\u2014\u2014\u901a\u8fc7\u4f20\u611f\u5668\u5b9e\u65f6\u76d1\u6d4b\u7a7a\u6c14\u4e2d\u80fa\u7c7b\u6d53\u5ea6\uff0c\u4e00\u65e6\u8d85\u6807\uff0c\u81ea\u52a8\u542f\u52a8\u5f3a\u6392\u98ce\u5e76\u53d1\u51fa\u8b66\u62a5\u3002\u8fd9\u6280\u672f\u542c\u7740\u9ad8\u79d1\u6280\uff0c\u5176\u5b9e\u539f\u7406\u5f88\u7b80\u5355\uff1a\u5c31\u662f\u7ed9\u5b9e\u9a8c\u5ba4\u88c5\u4e86\u4e2a\u201c\u7535\u5b50\u9f3b\u201d\u3002<\/p>\n<p>\u516b\u3001\u7ed3\u8bed\uff1a\u5c0a\u91cd\u6bcf\u4e00\u79cd\u5316\u5b66\u7269\u8d28\u7684\u201c\u6027\u683c\u201d<\/p>\n<p>TMEDA\u5c31\u50cf\u4e00\u4e2a\u624d\u534e\u6a2a\u6ea2\u4f46\u813e\u6c14\u53e4\u602a\u7684\u540c\u4e8b\uff1a\u80fd\u529b\u51fa\u4f17\uff0c\u4f46\u603b\u5728\u4f60\u4e0d\u6ce8\u610f\u65f6\u201c\u653e\u6bd2\u201d\u3002\u6211\u4eec\u4e0d\u80fd\u56e0\u4e3a\u5b83\u96be\u95fb\u5c31\u5426\u5b9a\u5b83\u7684\u4ef7\u503c\uff0c\u4e5f\u4e0d\u80fd\u56e0\u4e3a\u5b83\u6709\u7528\u5c31\u5ffd\u89c6\u5b83\u7684\u98ce\u9669\u3002<\/p>\n<p>\u5728\u5316\u5b66\u4e16\u754c\u91cc\uff0c\u6ca1\u6709\u7edd\u5bf9\u7684\u597d\u4e0e\u574f\uff0c\u53ea\u6709\u662f\u5426\u88ab\u6b63\u786e\u4f7f\u7528\u3002TMEDA\u6559\u4f1a\u6211\u4eec\u7684\uff0c\u4e0d\u4ec5\u662f\u5982\u4f55\u505a\u597d\u4e00\u4e2a\u5b9e\u9a8c\uff0c\u66f4\u662f\u5982\u4f55\u4e0e\u5371\u9669\u5171\u5904\u2014\u2014\u4fdd\u6301\u8b66\u60d5\uff0c\u505a\u597d\u9632\u62a4\uff0c\u5fc3\u5b58\u656c\u754f\u3002<\/p>\n<p>\u540e\uff0c\u9001\u6240\u6709\u5728\u5b9e\u9a8c\u5ba4\u594b\u6218\u7684\u540c\u4ec1\u4e00\u53e5\u8bdd\uff1a<br \/>\n\u201c\u4f60\u53ef\u4ee5\u4e0d\u6015\u53cd\u5e94\u7206\u70b8\uff0c\u4f46\u5343\u4e07\u522b\u5c0f\u770b\u4e00\u74f6TMEDA\u7684\u5a01\u529b\u3002\u5b83\u53ef\u80fd\u4e0d\u4f1a\u70b8\u6389\u4f60\u7684\u88c5\u7f6e\uff0c\u4f46\u4e00\u5b9a\u80fd\u70b8\u6389\u4f60\u4e00\u6574\u5929\u7684\u597d\u5fc3\u60c5\u3002\u201d<\/p>\n<hr \/>\n<p><strong>\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n<ol>\n<li>\n<p>Smith, M. B., &amp; March, J. (2007). <em>March&#8217;s Advanced Organic Chemistry: Reactions, Mechanisms, and Structure<\/em> (6th ed.). Wiley-Interscience.<br \/>\n\u2014\u2014 \u8be6\u7ec6\u4ecb\u7ecd\u4e86TMEDA\u5728\u6709\u673a\u91d1\u5c5e\u53cd\u5e94\u4e2d\u7684\u914d\u4f4d\u4f5c\u7528\u3002\n<\/li>\n<li>\n<p>Carey, F. A., &amp; Sundberg, R. J. (2007). <em>Advanced Organic Chemistry: Part A: Structure and Mechanisms<\/em> (5th ed.). Springer.<br \/>\n\u2014\u2014 \u8ba8\u8bba\u4e86TMEDA\u5bf9\u6709\u673a\u9502\u8bd5\u5242\u7a33\u5b9a\u6027\u7684\u5f71\u54cd\u3002\n<\/li>\n<li>\n<p>Zhang, Y., et al. (2020). &quot;TMEDA-assisted copper-catalyzed C\u2013N coupling reactions under mild conditions.&quot; <em>Journal of Organic Chemistry<\/em>, 85(12), 7890\u20137898.<br \/>\n\u2014\u2014 \u5c55\u793a\u4e86TMEDA\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u65b0\u5e94\u7528\u3002\n<\/li>\n<li>\n<p>National Institute for Occupational Safety and Health (NIOSH). (2021). <em>Pocket Guide to Chemical Hazards: N,N,N&#8217;,N&#8217;-Tetramethylethylenediamine<\/em>.<br \/>\n\u2014\u2014 \u63d0\u4f9b\u4e86TMEDA\u7684\u804c\u4e1a\u66b4\u9732\u9650\u503c\u548c\u5b89\u5168\u64cd\u4f5c\u5efa\u8bae\u3002\n<\/li>\n<li>\n<p>European Chemicals Agency (ECHA). (2023). <em>Registration Dossier for TMEDA<\/em>.<br \/>\n\u2014\u2014 \u5305\u542b\u6bd2\u7406\u5b66\u3001\u751f\u6001\u6bd2\u7406\u5b66\u53ca\u98ce\u9669\u8bc4\u4f30\u6570\u636e\u3002\n<\/li>\n<li>\n<p>\u674e\u4f1f, \u738b\u5f3a. (2019). &quot;\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55.&quot; <em>\u5316\u5b66\u901a\u62a5<\/em>, 82(5), 432\u2013438.<br \/>\n\u2014\u2014 \u7efc\u8ff0\u4e86TMEDA\u5728\u56fd\u5185\u79d1\u7814\u4e2d\u7684\u4f7f\u7528\u73b0\u72b6\u3002\n<\/li>\n<li>\n<p>OSHA. (2022). <em>Hazardous Waste Operations and Emergency Response (HAZWOPER)<\/em>.<br \/>\n\u2014\u2014 \u7f8e\u56fd\u5bf9\u6325\u53d1\u6027\u80fa\u7c7b\u5316\u5b66\u54c1\u7684\u7ba1\u7406\u89c4\u8303\u3002\n<\/li>\n<li>\n<p>\u5f20\u660e\u534e, \u7b49. (2021). &quot;\u5b9e\u9a8c\u5ba4\u6325\u53d1\u6027\u6709\u673a\u7269\u66b4\u9732\u5bf9\u79d1\u7814\u4eba\u5458\u5065\u5eb7\u5f71\u54cd\u7684\u8c03\u67e5.&quot; <em>\u4e2d\u56fd\u804c\u4e1a\u533b\u5b66<\/em>, 48(3), 267\u2013271.<br \/>\n\u2014\u2014 \u57fa\u4e8e\u56fd\u5185\u9ad8\u6821\u7684\u5b9e\u8bc1\u7814\u7a76\uff0c\u6307\u51faTMEDA\u7b49\u7269\u8d28\u5bf9\u5b9e\u9a8c\u4eba\u5458\u7684\u5fc3\u7406\u5f71\u54cd\u3002\n<\/li>\n<li>\n<p>Reichardt, C., &amp; Welton, T. (2011). <em>Solvents and Solvent Effects in Organic Chemistry<\/em> (4th ed.). Wiley-VCH.<br \/>\n\u2014\u2014 \u5206\u6790\u4e86TMEDA\u4f5c\u4e3a\u52a9\u6eb6\u5242\u7684\u6781\u6027\u6548\u5e94\u3002\n<\/li>\n<li>\n<p>\u9648\u5fd7\u8fdc. 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