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decoding=\"async\" src=\"\/images\/16.jpg\" alt=\"\"><\/p>\n<ol>\n<li>\u91d1\u5c5e\u50ac\u5316\u5242\u66ff\u4ee3<\/li>\n<\/ol>\n<p>\u8fd9\u7c7b\u66ff\u4ee3\u54c1\u4ecd\u5c5e\u4e8e\u91d1\u5c5e\u50ac\u5316\u8303\u7574\uff0c\u4f46\u9009\u7528\u66f4\u73af\u4fdd\u7684\u91d1\u5c5e\u79bb\u5b50\u3002\u4f8b\u5982\uff1a<\/p>\n<ul>\n<li><strong>\u94cb\u50ac\u5316\u5242<\/strong>\uff1a\u5982\u5f02\u8f9b\u9178\u94cb\u3001\u65b0\u7678\u9178\u94cb\u3002\u94cb\u5143\u7d20\u6bd2\u6027\u4f4e\uff0c\u751f\u7269\u964d\u89e3\u6027\u597d\uff0c\u4e14\u50ac\u5316\u6d3b\u6027\u63a5\u8fd1\u8f9b\u9178\u4e9a\u9521\u3002\u76ee\u524d\u5728\u8f6f\u8d28\u6ce1\u6cab\u4e2d\u5df2\u6709\u6210\u529f\u5e94\u7528\u3002<\/li>\n<li><strong>\u950c\u50ac\u5316\u5242<\/strong>\uff1a\u5982\u950c\u3001\u8f9b\u9178\u950c\u3002\u6210\u672c\u4f4e\uff0c\u4f46\u50ac\u5316\u6548\u7387\u7a0d\u5f31\uff0c\u591a\u7528\u4e8e\u5bf9\u6027\u80fd\u8981\u6c42\u4e0d\u9ad8\u7684\u573a\u5408\u3002<\/li>\n<li><strong>\u9506\u50ac\u5316\u5242<\/strong>\uff1a\u65b0\u5174\u9009\u624b\uff0c\u70ed\u7a33\u5b9a\u6027\u597d\uff0c\u8010\u6c34\u89e3\uff0c\u4f46\u4ef7\u683c\u8f83\u9ad8\uff0c\u5c1a\u672a\u5927\u89c4\u6a21\u666e\u53ca\u3002<\/li>\n<\/ul>\n<ol start=\"2\">\n<li>\u975e\u91d1\u5c5e\u50ac\u5316\u5242\u66ff\u4ee3<\/li>\n<\/ol>\n<p>\u8fd9\u662f\u8fd1\u5e74\u6765\u7684\u201c\u9ed1\u9a6c\u201d\u9886\u57df\uff0c\u5b8c\u5168\u6446\u8131\u91d1\u5c5e\u4f9d\u8d56\uff0c\u4ee3\u8868\u4ea7\u54c1\u5305\u62ec\uff1a<\/p>\n<ul>\n<li><strong>\u80fa\u7c7b\u50ac\u5316\u5242<\/strong>\uff1a\u5982\u4e8c\u7532\u57fa\u73af\u5df1\u80fa\uff08DMCHA\uff09\u3001\u53cc\u5417\u5549\u4e8c\u4e59\u57fa\u919a\uff08DMDEE\uff09\u3002\u5b83\u4eec\u901a\u8fc7\u78b1\u6027\u50ac\u5316\u4fc3\u8fdb\u53cd\u5e94\uff0c\u4f46\u53ef\u80fd\u5e26\u6765\u6c14\u5473\u548c\u6325\u53d1\u6027\u95ee\u9898\u3002<\/li>\n<li><strong>\u6709\u673a\u9178\u76d0<\/strong>\uff1a\u5982\u918b\u9178\u94be\u3001\u8f9b\u9178\u94be\u3002\u5728\u7279\u5b9a\u4f53\u7cfb\u4e2d\u8868\u73b0\u826f\u597d\uff0c\u4f46\u5bf9\u6c34\u5206\u654f\u611f\uff0c\u50a8\u5b58\u8981\u6c42\u9ad8\u3002<\/li>\n<li><strong>\u79bb\u5b50\u6db2\u4f53<\/strong>\uff1a\u65b0\u578b\u7eff\u8272\u6eb6\u5242\u517c\u50ac\u5316\u5242\uff0c\u50ac\u5316\u6548\u7387\u9ad8\uff0c\u53ef\u56de\u6536\uff0c\u4f46\u6210\u672c\u9ad8\u6602\uff0c\u5c1a\u5904\u5b9e\u9a8c\u5ba4\u9636\u6bb5\u3002<\/li>\n<\/ul>\n<ol start=\"3\">\n<li>\u65e0\u50ac\u5316\u5242\u4f53\u7cfb<\/li>\n<\/ol>\n<p>\u6fc0\u8fdb\u7684\u8def\u7ebf\u2014\u2014\u5e72\u8106\u4e0d\u7528\u50ac\u5316\u5242\u3002\u901a\u8fc7\u8c03\u6574\u539f\u6599\u914d\u6bd4\u3001\u5f15\u5165\u6d3b\u6027\u57fa\u56e2\u6216\u91c7\u7528\u65b0\u578b\u5f02\u6c30\u9178\u916f\uff0c\u5b9e\u73b0\u81ea\u50ac\u5316\u53cd\u5e94\u3002\u4f8b\u5982\uff0c\u67d0\u4e9b\u6539\u6027MDI\uff08\u4e8c\u82ef\u57fa\u7532\u70f7\u4e8c\u5f02\u6c30\u9178\u916f\uff09\u5728\u52a0\u70ed\u6761\u4ef6\u4e0b\u53ef\u81ea\u884c\u5f15\u53d1\u805a\u5408\u3002\u4e0d\u8fc7\uff0c\u8fd9\u79cd\u65b9\u6cd5\u5bf9\u5de5\u827a\u63a7\u5236\u8981\u6c42\u6781\u9ad8\uff0c\u76ee\u524d\u4ec5\u9002\u7528\u4e8e\u7279\u5b9a\u4ea7\u54c1\u3002<\/p>\n<p>\u4e0b\u8868\u5bf9\u6bd4\u4e86\u51e0\u79cd\u4e3b\u6d41\u66ff\u4ee3\u54c1\u7684\u6027\u80fd\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u66ff\u4ee3\u54c1\u7c7b\u578b<\/th>\n<th>\u4ee3\u8868\u7269\u8d28<\/th>\n<th>\u50ac\u5316\u6548\u7387<\/th>\n<th>\u6bd2\u6027<\/th>\n<th>\u6210\u672c<\/th>\n<th>\u73af\u4fdd\u6027<\/th>\n<th>\u5e94\u7528\u6210\u719f\u5ea6<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u8f9b\u9178\u4e9a\u9521<\/td>\n<td>\u4e8c\u8f9b\u9178\u4e9a\u9521<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u4e2d<\/td>\n<td>\u4f4e<\/td>\n<td>\u5dee<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u5f02\u8f9b\u9178\u94cb<\/td>\n<td>Bi(Oct)\u2083<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u4f4e<\/td>\n<td>\u4e2d<\/td>\n<td>\u597d<\/td>\n<td>\u4e2d<\/td>\n<\/tr>\n<tr>\n<td>\u950c<\/td>\n<td>Zn(OAc)\u2082<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u4f4e<\/td>\n<td>\u4f4e<\/td>\n<td>\u597d<\/td>\n<td>\u4e2d<\/td>\n<\/tr>\n<tr>\n<td>DMCHA<\/td>\n<td>\u4e8c\u7532\u57fa\u73af\u5df1\u80fa<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u4e2d<\/td>\n<td>\u4e2d<\/td>\n<td>\u4e2d<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>DMDEE<\/td>\n<td>\u53cc\u5417\u5549\u4e8c\u4e59\u57fa\u919a<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u4e2d<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u918b\u9178\u94be<\/td>\n<td>KOAc<\/td>\n<td>\u2605\u2605\u2606\u2606\u2606<\/td>\n<td>\u4f4e<\/td>\n<td>\u4f4e<\/td>\n<td>\u597d<\/td>\n<td>\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u79bb\u5b50\u6db2\u4f53<\/td>\n<td>[BMIM][BF\u2084]<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u4f4e<\/td>\n<td>\u6781\u9ad8<\/td>\n<td>\u4f18<\/td>\n<td>\u4f4e<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u8868\u4e2d\u53ef\u89c1\uff0c\u76ee\u524d\u5c1a\u65e0\u4e00\u79cd\u66ff\u4ee3\u54c1\u80fd\u5728\u6548\u7387\u3001\u6210\u672c\u3001\u73af\u4fdd\u4e09\u65b9\u9762\u5168\u9762\u8d85\u8d8a\u8f9b\u9178\u4e9a\u9521\u3002\u4f46\u201c\u7efc\u5408\u5f97\u5206\u201d\u9ad8\u7684\uff0c\u5f53\u5c5e\u94cb\u50ac\u5316\u5242\u548c\u90e8\u5206\u80fa\u7c7b\u50ac\u5316\u5242\u3002\u5c24\u5176\u662f\u94cb\u7cfb\u4ea7\u54c1\uff0c\u5df2\u88ab\u591a\u5bb6\u8de8\u56fd\u4f01\u4e1a\u5217\u4e3a\u201c\u4e0b\u4e00\u4ee3\u805a\u6c28\u916f\u50ac\u5316\u5242\u201d\u7684\u9996\u9009\u3002<\/p>\n<p>\u4e94\u3001\u6280\u672f\u74f6\u9888\u4e0e\u672a\u6765\u65b9\u5411<\/p>\n<p>\u66ff\u4ee3\u4e4b\u8def\uff0c\u9053\u963b\u4e14\u957f\u3002\u5f53\u524d\u73af\u4fdd\u66ff\u4ee3\u54c1\u9762\u4e34\u4e09\u5927\u96be\u9898\uff1a<\/p>\n<p>\u4e00\u662f<strong>\u50ac\u5316\u6548\u7387\u4e0e\u9009\u62e9\u6027\u7684\u5e73\u8861<\/strong>\u3002\u8bb8\u591a\u73af\u4fdd\u50ac\u5316\u5242\u867d\u65e0\u6bd2\uff0c\u4f46\u53cd\u5e94\u901f\u5ea6\u6162\uff0c\u6216\u5bfc\u81f4\u526f\u53cd\u5e94\u589e\u591a\uff0c\u5f71\u54cd\u4ea7\u54c1\u6027\u80fd\u3002\u6bd4\u5982\uff0c\u67d0\u4e9b\u80fa\u7c7b\u50ac\u5316\u5242\u4f1a\u52a0\u901f\u51dd\u80f6\u53cd\u5e94\uff0c\u5374\u6291\u5236\u53d1\u6ce1\uff0c\u5bfc\u81f4\u6ce1\u6cab\u5bc6\u5ea6\u4e0d\u5747\u3002<\/p>\n<p>\u4e8c\u662f<strong>\u6210\u672c\u95ee\u9898<\/strong>\u3002\u4ee5\u5f02\u8f9b\u9178\u94cb\u4e3a\u4f8b\uff0c\u4ef7\u683c\u7ea6\u4e3a\u8f9b\u9178\u4e9a\u9521\u76842~3\u500d\u3002\u5728\u5229\u6da6\u5fae\u8584\u7684\u4e2d\u4f4e\u7aef\u5e02\u573a\uff0c\u4f01\u4e1a\u96be\u4ee5\u627f\u53d7\u3002<\/p>\n<p>\u4e09\u662f<strong>\u4f9b\u5e94\u94fe\u7a33\u5b9a\u6027<\/strong>\u3002\u94cb\u3001\u9506\u7b49\u91d1\u5c5e\u8d44\u6e90\u76f8\u5bf9\u7a00\u7f3a\uff0c\u5168\u7403\u4ea7\u91cf\u6709\u9650\uff0c\u5927\u89c4\u6a21\u63a8\u5e7f\u53ef\u80fd\u5f15\u53d1\u539f\u6750\u6599\u4e89\u593a\u6218\u3002<\/p>\n<p>\u672a\u6765\u7684\u53d1\u5c55\u65b9\u5411\uff0c\u6216\u8bb8\u4e0d\u5728\u201c\u66ff\u4ee3\u201d\uff0c\u800c\u5728\u201c\u91cd\u6784\u201d\u3002\u6bd4\u5982\uff1a<\/p>\n<ul>\n<li><strong>\u590d\u5408\u50ac\u5316\u4f53\u7cfb<\/strong>\uff1a\u5c06\u5c11\u91cf\u9ad8\u6548\u50ac\u5316\u5242\u4e0e\u73af\u4fdd\u52a9\u5242\u590d\u914d\uff0c\u5b9e\u73b0\u201c1+1&gt;2\u201d\u7684\u6548\u679c\u3002\u4f8b\u5982\uff0c\u94cb-\u80fa\u534f\u540c\u50ac\u5316\uff0c\u65e2\u80fd\u964d\u4f4e\u91d1\u5c5e\u7528\u91cf\uff0c\u53c8\u80fd\u63d0\u5347\u53cd\u5e94\u901f\u5ea6\u3002<\/li>\n<li><strong>\u667a\u80fd\u54cd\u5e94\u578b\u50ac\u5316\u5242<\/strong>\uff1a\u5f00\u53d1\u6e29\u5ea6\u3001pH\u6216\u5149\u54cd\u5e94\u7684\u50ac\u5316\u5242\uff0c\u5b9e\u73b0\u201c\u6309\u9700\u50ac\u5316\u201d\uff0c\u51cf\u5c11\u6b8b\u7559\u3002<\/li>\n<li><strong>\u751f\u7269\u57fa\u50ac\u5316\u5242<\/strong>\uff1a\u5229\u7528\u690d\u7269\u63d0\u53d6\u7269\u6216\u5fae\u751f\u7269\u4ee3\u8c22\u4ea7\u7269\u4f5c\u4e3a\u50ac\u5316\u5a92\u4ecb\uff0c\u771f\u6b63\u5b9e\u73b0\u201c\u4ece\u6447\u7bee\u5230\u6447\u7bee\u201d\u7684\u7eff\u8272\u5faa\u73af\u3002<\/li>\n<\/ul>\n<p>\u516d\u3001\u7ed3\u8bed\uff1a\u544a\u522b\u4e0d\u662f\u7ec8\u70b9<\/p>\n<p>\u8f9b\u9178\u4e9a\u9521\u7684\u6545\u4e8b\uff0c\u50cf\u6781\u4e86\u5de5\u4e1a\u6587\u660e\u7684\u4e00\u6bb5\u7f29\u5f71\u2014\u2014\u6211\u4eec\u66fe\u4f9d\u8d56\u5b83\u63a8\u52a8\u6280\u672f\u8fdb\u6b65\uff0c\u5982\u4eca\u53c8\u56e0\u73af\u5883\u4ee3\u4ef7\u800c\u4e0d\u5f97\u4e0d\u4e0e\u4e4b\u544a\u522b\u3002\u4f46\u544a\u522b\u4e0d\u7b49\u4e8e\u6d88\u5931\uff0c\u800c\u662f\u4e00\u79cd\u8fdb\u5316\u3002\u6b63\u5982\u8001\u5f0f\u706f\u6ce1\u88abLED\u53d6\u4ee3\uff0c\u9a6c\u8f66\u8ba9\u4f4d\u4e8e\u6c7d\u8f66\uff0c\u6bcf\u4e00\u6b21\u6280\u672f\u66f4\u66ff\uff0c\u90fd\u662f\u4eba\u7c7b\u4e0e\u81ea\u7136\u91cd\u65b0\u8c08\u5224\u7684\u8fc7\u7a0b\u3002<\/p>\n<p>\u672a\u6765\uff0c\u8f9b\u9178\u4e9a\u9521\u6216\u8bb8\u4f1a\u50cf\u6050\u9f99\u4e00\u6837\uff0c\u6210\u4e3a\u5316\u5de5\u53f2\u4e0a\u7684\u201c\u6d3b\u5316\u77f3\u201d\uff0c\u88ab\u9648\u5217\u5728\u6559\u79d1\u4e66\u7684\u67d0\u4e00\u9875\u3002\u4f46\u5b83\u7684\u201c\u57fa\u56e0\u201d\u2014\u2014\u9ad8\u6548\u50ac\u5316\u7406\u5ff5\uff0c\u4ecd\u4f1a\u4ee5\u66f4\u7eff\u8272\u3001\u66f4\u667a\u6167\u7684\u5f62\u5f0f\u5ef6\u7eed\u4e0b\u53bb\u3002<\/p>\n<p>\u5728\u73af\u4fdd\u4e0e\u6027\u80fd\u7684\u5929\u5e73\u4e0a\uff0c\u6211\u4eec\u7ec8\u5c06\u627e\u5230\u65b0\u7684\u5e73\u8861\u70b9\u3002\u6bd5\u7adf\uff0c\u4eba\u7c7b\u7684\u667a\u6167\uff0c\u4ece\u6765\u4e0d\u6b62\u4e8e\u201c\u7528\u201d\u6216\u201c\u4e0d\u7528\u201d\uff0c\u800c\u5728\u4e8e\u201c\u5982\u4f55\u7528\u5f97\u66f4\u597d\u201d\u3002<\/p>\n<p>\u4e03\u3001\u53c2\u8003\u6587\u732e<\/p>\n<ol>\n<li>\u4e2d\u56fd\u805a\u6c28\u916f\u5de5\u4e1a\u534f\u4f1a. \u300a2023\u5e74\u4e2d\u56fd\u805a\u6c28\u916f\u884c\u4e1a\u5e74\u5ea6\u62a5\u544a\u300b. \u5317\u4eac: \u4e2d\u56fd\u5316\u5de5\u51fa\u7248\u793e, 2023.  <\/li>\n<li>European Chemicals Agency (ECHA). &quot;Substances of Very High Concern (SVHC) List.&quot; 2023 Update.  <\/li>\n<li>U.S. Environmental Protection Agency (EPA). &quot;Organotin Compounds: Risk Assessment and Regulatory Status.&quot; EPA-745-R-22-001, 2022.  <\/li>\n<li>\u5f20\u7acb\u65b0, \u674e\u534e. \u300a\u6709\u673a\u9521\u50ac\u5316\u5242\u7684\u73af\u5883\u884c\u4e3a\u4e0e\u66ff\u4ee3\u6280\u672f\u8fdb\u5c55\u300b. \u5316\u5de5\u8fdb\u5c55, 2021, 40(5): 2345-2352.  <\/li>\n<li>Wilkes, G. L., et al. &quot;Catalysis in Polyurethane Systems: A Review of Mechanisms and Alternatives.&quot; <em>Progress in Polymer Science<\/em>, 2020, 108: 101289.  <\/li>\n<li>\u738b\u5fd7\u5f3a, \u9648\u6653\u5cf0. \u300a\u94cb\u57fa\u50ac\u5316\u5242\u5728\u805a\u6c28\u916f\u4e2d\u7684\u5e94\u7528\u7814\u7a76\u300b. \u5851\u6599\u5de5\u4e1a, 2022, 50(3): 88-93.  <\/li>\n<li>Trochimczuk, A. W., et al. &quot;Tin-free catalysts for polyurethane synthesis: A sustainable approach.&quot; <em>Green Chemistry<\/em>, 2019, 21(12): 3210-3225.  <\/li>\n<li>\u56fd\u5bb6\u751f\u6001\u73af\u5883\u90e8. \u300a\u91cd\u70b9\u7ba1\u63a7\u65b0\u6c61\u67d3\u7269\u6e05\u5355\uff082022\u5e74\u7248\uff09\u300b. \u516c\u544a2022\u5e74\u7b2c50\u53f7.  <\/li>\n<li>Oertel, G. <em>Polyurethane Handbook<\/em>. 3rd ed. Munich: Hanser Publishers, 2006.  <\/li>\n<li>\u5218\u4f1f, \u8d75\u660e. \u300a\u73af\u4fdd\u578b\u805a\u6c28\u916f\u50ac\u5316\u5242\u7684\u5f00\u53d1\u4e0e\u5e02\u573a\u524d\u666f\u300b. \u5316\u5de5\u65b0\u578b\u6750\u6599, 2023, 51(4): 45-50.<\/li>\n<\/ol>\n<p>\uff08\u5168\u6587\u7ea63100\u5b57\uff09<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n<p>===========================================================<\/p>\n<h2>\u516c\u53f8\u5176\u5b83\u4ea7\u54c1\u5c55\u793a:<\/h2>\n<ul>\n<li>\n<h3>NT CAT T-12 \u9002\u7528\u4e8e\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff0c\u5feb\u901f\u56fa\u5316\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT UL1 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