{"id":13029,"date":"2025-07-23T11:08:14","date_gmt":"2025-07-23T03:08:14","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/13029"},"modified":"2025-07-23T11:08:14","modified_gmt":"2025-07-23T03:08:14","slug":"dbu%e4%ba%8c%e6%b0%ae%e6%9d%82%e4%ba%8c%e7%8e%af%e7%9a%84%e4%bd%8e%e6%b0%94%e5%91%b3%e7%89%b9%e6%80%a7%e4%b8%8e%e7%8e%af%e5%a2%83%e5%8f%8b%e5%a5%bd%e6%80%a7%e8%80%83%e9%87%8f","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/13029","title":{"rendered":"DBU\u4e8c\u6c2e\u6742\u4e8c\u73af\u7684\u4f4e\u6c14\u5473\u7279\u6027\u4e0e\u73af\u5883\u53cb\u597d\u6027\u8003\u91cf"},"content":{"rendered":"<p>\u5728\u5316\u5de5\u8fd9\u4e2a\u4e94\u5149\u5341\u8272\u7684\u5927\u821e\u53f0\u4e0a\uff0c\u5404\u7c7b\u6eb6\u5242\u3001\u50ac\u5316\u5242\u3001\u52a9\u5242\u8f6e\u756a\u767b\u573a\uff0c\u50cf\u6781\u4e86\u83dc\u5e02\u573a\u91cc\u5406\u559d\u7684\u644a\u8d29\u2014\u2014\u6709\u7684\u9999\u6c14\u6251\u9f3b\uff0c\u6709\u7684\u81ed\u6c14\u718f\u5929\u3002\u800c\u4eca\u5929\u6211\u4eec\u8981\u804a\u7684\u8fd9\u4f4d\u201c\u6f14\u5458\u201d\uff0c\u65e2\u4e0d\u5f20\u626c\u4e5f\u4e0d\u523a\u9f3b\uff0c\u5374\u5728\u9ad8\u5206\u5b50\u5408\u6210\u3001\u533b\u836f\u7814\u53d1\u548c\u7cbe\u7ec6\u5316\u5de5\u9886\u57df\u6084\u7136\u8d70\u7ea2\uff0c\u5b83\u5c31\u662fDBU\uff0c\u5168\u540d1,8-\u4e8c\u6c2e\u6742\u4e8c\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff081,8-Diazabicyclo[5.4.0]undec-7-ene\uff09\u3002\u542c\u8d77\u6765\u540d\u5b57\u6709\u70b9\u62d7\u53e3\uff0c\u50cf\u662f\u4ece\u5316\u5b66\u8bfe\u672c\u91cc\u9003\u51fa\u6765\u7684\u602a\u517d\uff0c\u4f46\u5b83\u5176\u5b9e\u662f\u4e2a\u4f4e\u8c03\u53c8\u5b9e\u7528\u7684\u201c\u8001\u597d\u4eba\u201d\u3002<\/p>\n<h3>\u4e00\u3001DBU\u662f\u8c01\uff1f\u4e00\u4e2a\u201c\u78b1\u6027\u6e29\u548c\u3001\u813e\u6c14\u597d\u201d\u7684\u7ec5\u58eb<\/h3>\n<p>DBU\u4e0d\u662f\u90a3\u79cd\u8ba9\u4eba\u4e00\u95fb\u5c31\u60f3\u9003\u7684\u5316\u5b66\u7269\u8d28\u3002\u4f60\u53ef\u80fd\u7528\u8fc7\u4e09\u4e59\u80fa\uff0c\u90a3\u73a9\u610f\u513f\u4e00\u5f00\u74f6\uff0c\u4eff\u4f5b\u6574\u4e2a\u5b9e\u9a8c\u5ba4\u90fd\u88ab\u4e00\u80a1\u201c\u9c7c\u5e02\u6e05\u6668\u201d\u7684\u6c14\u606f\u5360\u9886\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cDBU\u5c31\u50cf\u662f\u521a\u55b7\u4e86\u6de1\u9999\u6c34\u7684\u5316\u5b66\u754c\u7ec5\u58eb\uff0c\u6c14\u5473\u8f7b\u5fae\uff0c\u51e0\u4e4e\u53ef\u4ee5\u5ffd\u7565\u4e0d\u8ba1\u3002<\/p>\n<p>\u8fd9\u5f97\u76ca\u4e8e\u5b83\u7684\u5206\u5b50\u7ed3\u6784\u2014\u2014\u53cc\u73af\u7ed3\u6784\u8ba9\u5b83\u6bd4\u666e\u901a\u8102\u80aa\u80fa\u66f4\u7a33\u5b9a\uff0c\u6325\u53d1\u6027\u66f4\u4f4e\u3002\u6362\u53e5\u8bdd\u8bf4\uff0c\u5b83\u4e0d\u50cf\u90a3\u4e9b\u201c\u7231\u51fa\u98ce\u5934\u201d\u7684\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u603b\u60f3\u901a\u8fc7\u5f3a\u70c8\u7684\u6c14\u5473\u5237\u5b58\u5728\u611f\u3002DBU\u66f4\u613f\u610f\u9ed8\u9ed8\u505a\u4e8b\uff0c\u505a\u5b8c\u5c31\u9000\u573a\uff0c\u4e0d\u7559\u75d5\u8ff9\u3002<\/p>\n<p>\u5f53\u7136\uff0c\u5b83\u4e5f\u4e0d\u662f\u4e2a\u8f6f\u67ff\u5b50\u3002\u867d\u7136\u6c14\u5473\u6e29\u548c\uff0c\u4f46\u78b1\u6027\u5374\u4e0d\u5bb9\u5c0f\u89d1\u3002\u5b83\u7684pKa\u503c\u572812\u5de6\u53f3\uff0c\u5728\u6709\u673a\u78b1\u4e2d\u5c5e\u4e8e\u201c\u4e2d\u4e0a\u6c34\u5e73\u201d\u3002\u8fd9\u610f\u5473\u7740\u5b83\u65e2\u80fd\u6709\u6548\u50ac\u5316\u53cd\u5e94\uff0c\u53c8\u4e0d\u4f1a\u50cf\u6c22\u6c27\u5316\u94a0\u90a3\u6837\u201c\u66b4\u8e81\u201d\uff0c\u52a8\u4e0d\u52a8\u5c31\u628a\u5e95\u7269\u6c34\u89e3\u5f97\u9762\u76ee\u5168\u975e\u3002<\/p>\n<h3>\u4e8c\u3001\u4f4e\u6c14\u5473\uff1a\u4e0d\u53ea\u662f\u4e3a\u4e86\u9f3b\u5b50\u8212\u670d<\/h3>\n<p>\u4e3a\u4ec0\u4e48\u4f4e\u6c14\u5473\u8fd9\u4e48\u91cd\u8981\uff1f\u96be\u9053\u5316\u5b66\u5bb6\u90fd\u6210\u4e86\u55c5\u89c9\u6d01\u7656\u60a3\u8005\uff1f<\/p>\n<p>\u8fd8\u771f\u5dee\u4e0d\u591a\u3002<\/p>\n<p>\u5728\u5236\u836f\u5382\u3001\u6d82\u6599\u8f66\u95f4\u6216\u8005\u7535\u5b50\u6750\u6599\u751f\u4ea7\u7ebf\uff0c\u957f\u671f\u66b4\u9732\u5728\u9ad8\u6325\u53d1\u6027\u80fa\u7c7b\u73af\u5883\u4e2d\uff0c\u4e0d\u4ec5\u5f71\u54cd\u5458\u5de5\u8212\u9002\u5ea6\uff0c\u8fd8\u53ef\u80fd\u5f15\u53d1\u5934\u75db\u3001\u6076\u5fc3\u751a\u81f3\u547c\u5438\u9053\u523a\u6fc0\u3002\u67d0\u4e9b\u5f3a\u6c14\u5473\u6eb6\u5242\u8fd8\u4f1a\u5bfc\u81f4\u201c\u529e\u516c\u5ba4\u6028\u6c14\u6307\u6570\u201d\u98d9\u5347\u2014\u2014\u8c01\u90fd\u4e0d\u60f3\u6bcf\u5929\u5bf9\u7740\u4e00\u74f6\u201c\u751f\u5316\u6b66\u5668\u201d\u5de5\u4f5c\u3002<\/p>\n<p>DBU\u7684\u6c14\u5473\u9608\u503c\u8fdc\u9ad8\u4e8e\u4f20\u7edf\u80fa\u7c7b\u3002\u7b80\u5355\u8bf4\uff0c\u5c31\u662f\u4f60\u5f97\u51d1\u5f97\u5f88\u8fd1\u624d\u80fd\u95fb\u5230\u4e00\u70b9\u70b9\u201c\u6de1\u6de1\u7684\u6c28\u5473\u6df7\u5408\u7740\u4e00\u70b9\u70b9\u6ce5\u571f\u6c14\u606f\u201d\uff0c\u800c\u4e14\u6301\u7eed\u65f6\u95f4\u6781\u77ed\u3002\u8fd9\u79cd\u201c\u6765\u65e0\u5f71\u53bb\u65e0\u8e2a\u201d\u7684\u7279\u8d28\uff0c\u8ba9\u5b83\u5728\u73b0\u4ee3\u7eff\u8272\u5de5\u5382\u4e2d\u8d8a\u6765\u8d8a\u53d7\u6b22\u8fce\u3002<\/p>\n<p>\u66f4\u91cd\u8981\u7684\u662f\uff0c\u4f4e\u6c14\u5473\u5f80\u5f80\u610f\u5473\u7740\u4f4e\u6325\u53d1\u6027\uff08VOC\uff09\uff0c\u800c\u4f4eVOC\u6b63\u662f\u73af\u4fdd\u6cd5\u89c4\u7d27\u76ef\u7684\u76ee\u6807\u3002\u6b27\u76dfREACH\u6cd5\u89c4\u3001\u7f8e\u56fdEPA\u6807\u51c6\u3001\u4e2d\u56fd\u300a\u6325\u53d1\u6027\u6709\u673a\u7269\u65e0\u7ec4\u7ec7\u6392\u653e\u63a7\u5236\u6807\u51c6\u300b\uff08GB 37822-2019\uff09\u90fd\u5bf9\u5de5\u4e1a\u5316\u5b66\u54c1\u7684VOC\u6392\u653e\u6709\u4e25\u683c\u9650\u5236\u3002DBU\u7684\u6cb8\u70b9\u9ad8\u8fbe276\u00b0C\uff0c\u5e38\u6e29\u4e0b\u51e0\u4e4e\u4e0d\u6325\u53d1\uff0c\u81ea\u7136\u6210\u4e86\u5408\u89c4\u754c\u7684\u201c\u6a21\u8303\u751f\u201d\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570\u9879<\/th>\n<th>DBU<\/th>\n<th>\u4e09\u4e59\u80fa\uff08TEA\uff09<\/th>\n<th>\u5421\u5576<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C\u2089H\u2081\u2087N<\/td>\n<td>C\u2086H\u2081\u2085N<\/td>\n<td>C\u2085H\u2085N<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>139.24 g\/mol<\/td>\n<td>101.19 g\/mol<\/td>\n<td>79.10 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>276\u00b0C<\/td>\n<td>89\u00b0C<\/td>\n<td>115\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>\u7ea621\u00b0C<\/td>\n<td>-114\u00b0C<\/td>\n<td>-41.6\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>pKa (\u5171\u8f6d\u9178)<\/td>\n<td>~12<\/td>\n<td>~10.8<\/td>\n<td>~5.2<\/td>\n<\/tr>\n<tr>\n<td>\u6c14\u5473\u5f3a\u5ea6<\/td>\n<td>\u8f7b\u5fae\uff0c\u7565\u5e26\u6c28\u5473<\/td>\n<td>\u5f3a\u70c8\u9c7c\u8165\u5473<\/td>\n<td>\u523a\u9f3b\u6076\u81ed<\/td>\n<\/tr>\n<tr>\n<td>VOC\u7b49\u7ea7<\/td>\n<td>\u6781\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d\u7b49<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u6eb6\u6027<\/td>\n<td>\u53ef\u6df7\u6eb6<\/td>\n<td>\u4e2d\u7b49\u53ef\u6eb6<\/td>\n<td>\u53ef\u6eb6<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u8fd9\u5f20\u8868\u53ef\u4ee5\u770b\u51fa\uff0cDBU\u5728\u6cb8\u70b9\u3001\u6c14\u5473\u3001VOC\u7b49\u65b9\u9762\u5168\u9762\u201c\u78be\u538b\u201d\u4f20\u7edf\u80fa\u7c7b\u3002\u5c24\u5176\u662f\u6cb8\u70b9\uff0c\u9ad8\u51fa\u4e00\u5927\u622a\uff0c\u610f\u5473\u7740\u5b83\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u5b89\u5206\u5b88\u5df1\uff0c\u4e0d\u4f1a\u8f7b\u6613\u201c\u6e9c\u201d\u8fdb\u7a7a\u6c14\u4e2d\u641e\u7834\u574f\u3002<\/p>\n<h3>\u4e09\u3001\u73af\u5883\u53cb\u597d\u6027\uff1a\u4e0d\u53ea\u662f\u201c\u4e0d\u81ed\u201d\u90a3\u4e48\u7b80\u5355<\/h3>\n<p>\u4f4e\u6c14\u5473\u53ea\u662f\u8868\u9762\u529f\u592b\uff0c\u771f\u6b63\u7684\u73af\u4fdd\u8fd8\u5f97\u770b\u751f\u6001\u6bd2\u6027\u3001\u751f\u7269\u964d\u89e3\u6027\u548c\u73af\u5883\u6301\u4e45\u6027\u3002<\/p>\n<p>DBU\u5728\u6c34\u4e2d\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u6027\uff0c\u4f46\u8fd9\u5e76\u4e0d\u610f\u5473\u7740\u5b83\u4f1a\u5bf9\u6c34\u4f53\u9020\u6210\u4e25\u91cd\u6c61\u67d3\u3002\u7814\u7a76\u8868\u660e\uff0cDBU\u5728\u597d\u6c27\u6761\u4ef6\u4e0b\u53ef\u88ab\u5fae\u751f\u7269\u90e8\u5206\u964d\u89e3\uff0c\u534a\u8870\u671f\u7ea6\u4e3a\u6570\u5929\u81f3\u4e24\u5468\uff0c\u5177\u4f53\u53d6\u51b3\u4e8e\u73af\u5883\u6761\u4ef6\u3002\u867d\u7136\u4e0d\u7b97\u201c\u901f\u964d\u9009\u624b\u201d\uff0c\u4f46\u4e5f\u7edd\u975e\u201c\u5343\u5e74\u4e0d\u8150\u201d\u7684\u987d\u56fa\u5206\u5b50\u3002<\/p>\n<p>\u66f4\u5173\u952e\u7684\u662f\uff0c\u5b83\u5bf9\u6c34\u751f\u751f\u7269\u7684\u6bd2\u6027\u76f8\u5bf9\u8f83\u4f4e\u3002\u6839\u636eOECD\u6d4b\u8bd5\u6807\u51c6\uff0cDBU\u5bf9\u53d1\u5149\u7ec6\u83cc\uff08\u5982\u8d39\u6c0f\u5f27\u83cc\uff09\u7684EC50\u503c\u5728100 mg\/L\u4ee5\u4e0a\uff0c\u5c5e\u4e8e\u201c\u4f4e\u6bd2\u201d\u8303\u7574\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5421\u5576\u7684EC50\u53ef\u4f4e\u81f310 mg\/L\u4ee5\u4e0b\uff0c\u582a\u79f0\u201c\u6c34\u4e2d\u5c0f\u9738\u738b\u201d\u3002<\/p>\n<p>\u6b64\u5916\uff0cDBU\u5728\u571f\u58e4\u4e2d\u7684\u5438\u9644\u80fd\u529b\u8f83\u5f3a\uff0c\u4e0d\u6613\u968f\u96e8\u6c34\u51b2\u5237\u8fdb\u5165\u5730\u4e0b\u6c34\u7cfb\u7edf\u3002\u8fd9\u4e00\u7279\u6027\u51cf\u5c11\u4e86\u5b83\u5bf9\u5730\u4e0b\u6c34\u6e90\u7684\u6f5c\u5728\u5a01\u80c1\uff0c\u4e5f\u964d\u4f4e\u4e86\u8fc1\u79fb\u6269\u6563\u7684\u98ce\u9669\u3002<\/p>\n<p>\u4e0d\u8fc7\uff0c\u6211\u4eec\u4e5f\u4e0d\u80fd\u628a\u5b83\u6367\u6210\u201c\u73af\u4fdd\u5723\u4eba\u201d\u3002DBU\u6bd5\u7adf\u662f\u6709\u673a\u78b1\uff0c\u5927\u91cf\u6392\u653e\u4ecd\u53ef\u80fd\u6539\u53d8\u5c40\u90e8pH\u503c\uff0c\u5f71\u54cd\u5fae\u751f\u7269\u7fa4\u843d\u3002\u56e0\u6b64\uff0c\u5de5\u4e1a\u4f7f\u7528\u4e2d\u4ecd\u9700\u914d\u5957\u5e9f\u6c34\u5904\u7406\u63aa\u65bd\uff0c\u6bd4\u5982\u6d3b\u6027\u70ad\u5438\u9644\u6216\u9ad8\u7ea7\u6c27\u5316\u5de5\u827a\u3002<\/p>\n<h3>\u56db\u3001\u5e94\u7528\u573a\u666f\uff1a\u4f4e\u8c03\u80cc\u540e\u7684\u201c\u5168\u80fd\u9009\u624b\u201d<\/h3>\n<p>\u522b\u770bDBU\u6027\u683c\u6e29\u548c\uff0c\u5e72\u8d77\u6d3b\u6765\u53ef\u4e00\u70b9\u4e0d\u542b\u7cca\u3002\u5b83\u5728\u591a\u4e2a\u9886\u57df\u90fd\u6709\u4eae\u773c\u8868\u73b0\uff1a<\/p>\n<h4>1. \u805a\u6c28\u916f\u6ce1\u6cab\u7684\u50ac\u5316\u5242<\/h4>\n<p>\u5728\u8f6f\u8d28\u548c\u786c\u8d28\u805a\u6c28\u916f\u6ce1\u6cab\u751f\u4ea7\u4e2d\uff0cDBU\u662f\u9ad8\u6548\u7684\u51dd\u80f6\u50ac\u5316\u5242\u3002\u5b83\u80fd\u52a0\u901f\u5f02\u6c30\u9178\u916f\u4e0e\u591a\u5143\u9187\u7684\u53cd\u5e94\uff0c\u540c\u65f6\u6291\u5236\u526f\u53cd\u5e94\uff0c\u63d0\u5347\u6ce1\u6cab\u7684\u5747\u5300\u6027\u548c\u529b\u5b66\u6027\u80fd\u3002\u76f8\u6bd4\u4f20\u7edf\u7684\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff08DBTDL\uff09\uff0cDBU\u4e0d\u542b\u91d1\u5c5e\uff0c\u907f\u514d\u4e86\u91cd\u91d1\u5c5e\u6b8b\u7559\u95ee\u9898\uff0c\u66f4\u7b26\u5408\u98df\u54c1\u5305\u88c5\u3001\u533b\u7597\u5668\u68b0\u7b49\u9ad8\u7aef\u5e94\u7528\u7684\u9700\u6c42\u3002<\/p>\n<h4>2. \u533b\u836f\u5408\u6210\u4e2d\u7684\u201c\u9690\u5f62\u63a8\u624b\u201d<\/h4>\n<p>\u5728\u836f\u7269\u4e2d\u95f4\u4f53\u5408\u6210\u4e2d\uff0cDBU\u5e38\u7528\u4e8e\u4fc3\u8fdb\u6d88\u9664\u53cd\u5e94\u3001Michael\u52a0\u6210\u3001\u73af\u5316\u53cd\u5e94\u7b49\u3002\u4f8b\u5982\uff0c\u5728\u5408\u6210\u6297\u75c5\u6bd2\u836f\u7269\u62c9\u7c73\u592b\u5b9a\uff08Lamivudine\uff09\u7684\u8fc7\u7a0b\u4e2d\uff0cDBU\u4f5c\u4e3a\u78b1\u50ac\u5316\u5242\uff0c\u5e2e\u52a9\u6784\u5efa\u5173\u952e\u7684\u624b\u6027\u4e2d\u5fc3\uff0c\u6536\u7387\u9ad8\u4e14\u526f\u4ea7\u7269\u5c11\u3002<\/p>\n<h4>3. \u7535\u5b50\u5316\u5b66\u54c1\u7684\u201c\u6e05\u6d01\u5e2e\u624b\u201d<\/h4>\n<p>\u5728\u534a\u5bfc\u4f53\u5236\u9020\u4e2d\uff0c\u5149\u523b\u80f6\u7684\u663e\u5f71\u6db2\u9700\u8981\u9ad8\u7eaf\u5ea6\u3001\u4f4e\u91d1\u5c5e\u79bb\u5b50\u7684\u78b1\u6027\u8bd5\u5242\u3002DBU\u56e0\u5176\u9ad8\u7eaf\u5ea6\u3001\u4f4e\u8150\u8680\u6027\u548c\u826f\u597d\u6eb6\u89e3\u6027\uff0c\u6210\u4e3a\u66ff\u4ee3\u4f20\u7edf\u56db\u7532\u57fa\u6c22\u6c27\u5316\u94f5\uff08TMAH\uff09\u7684\u7406\u60f3\u9009\u62e9\u4e4b\u4e00\u3002<\/p>\n<h4>4. CO\u2082\u6355\u83b7\u7684\u65b0\u661f<\/h4>\n<p>\u8fd1\u5e74\u6765\uff0cDBU\u5728\u4e8c\u6c27\u5316\u78b3\u5438\u6536\u65b9\u9762\u7684\u6f5c\u529b\u88ab\u5e7f\u6cdb\u6316\u6398\u3002\u5b83\u80fd\u4e0eCO\u2082\u5f62\u6210\u7a33\u5b9a\u7684\u78b3\u9178\u76d0\u52a0\u5408\u7269\uff0c\u4e14\u518d\u751f\u80fd\u8017\u8f83\u4f4e\u3002\u4e00\u4e9b\u7814\u7a76\u5c06\u5176\u4e0e\u9187\u7c7b\u6eb6\u5242\u590d\u914d\uff0c\u5f00\u53d1\u51fa\u65b0\u578b\u201c\u975e\u6c34\u80fa\u6cd5\u201d\u78b3\u6355\u96c6\u4f53\u7cfb\uff0c\u6709\u671b\u5e94\u7528\u4e8e\u71c3\u7164\u7535\u5382\u70df\u6c14\u5904\u7406\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5e94\u7528\u9886\u57df<\/th>\n<th>\u5178\u578b\u7528\u9014<\/th>\n<th>\u4f18\u52bf\u4f53\u73b0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u805a\u6c28\u916f<\/td>\n<td>\u6ce1\u6cab\u50ac\u5316\u5242<\/td>\n<td>\u65e0\u91d1\u5c5e\u3001\u4f4e\u6c14\u5473\u3001\u9ad8\u9009\u62e9\u6027<\/td>\n<\/tr>\n<tr>\n<td>\u533b\u836f\u5408\u6210<\/td>\n<td>\u7f29\u5408\/\u6d88\u9664\u53cd\u5e94<\/td>\n<td>\u9ad8\u6536\u7387\u3001\u526f\u53cd\u5e94\u5c11<\/td>\n<\/tr>\n<tr>\n<td>\u7535\u5b50\u6750\u6599<\/td>\n<td>\u5149\u523b\u80f6\u663e\u5f71<\/td>\n<td>\u4f4e\u91d1\u5c5e\u6b8b\u7559\u3001\u9ad8\u7eaf\u5ea6<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u5883\u5de5\u7a0b<\/td>\n<td>CO\u2082\u6355\u96c6<\/td>\n<td>\u53ef\u9006\u5438\u6536\u3001\u518d\u751f\u80fd\u8017\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u6d82\u6599\u6cb9\u58a8<\/td>\n<td>\u56fa\u5316\u4fc3\u8fdb\u5242<\/td>\n<td>\u63d0\u5347\u4ea4\u8054\u6548\u7387\u3001\u6539\u5584\u6d41\u5e73\u6027<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>\u4e94\u3001\u5b89\u5168\u4e0e\u64cd\u4f5c\uff1a\u6e29\u67d4\u4e0d\u4ee3\u8868\u65e0\u5bb3<\/h3>\n<p>\u5c3d\u7ba1DBU\u6574\u4f53\u8868\u73b0\u6e29\u548c\uff0c\u4f46\u4e5f\u4e0d\u80fd\u6389\u4ee5\u8f7b\u5fc3\u3002\u5b83\u4ecd\u5c5e\u4e8e\u78b1\u6027\u8150\u8680\u54c1\uff0c\u63a5\u89e6\u76ae\u80a4\u6216\u773c\u775b\u4f1a\u5f15\u8d77\u523a\u6fc0\u3002\u64cd\u4f5c\u65f6\u5efa\u8bae\u4f69\u6234\u9632\u62a4\u624b\u5957\u3001\u62a4\u76ee\u955c\uff0c\u5e76\u5728\u901a\u98ce\u826f\u597d\u7684\u73af\u5883\u4e2d\u8fdb\u884c\u3002<\/p>\n<p>\u5176LD50\uff08\u5927\u9f20\u7ecf\u53e3\uff09\u7ea6\u4e3a1.6 g\/kg\uff0c\u5c5e\u4e8e\u4e2d\u7b49\u6bd2\u6027\u7ea7\u522b\u3002\u867d\u4e0d\u81f3\u4e8e\u201c\u4e00\u53e3\u81f4\u547d\u201d\uff0c\u4f46\u7edd\u4e0d\u80fd\u62ff\u6765\u6ce1\u8336\u559d\u3002\u50a8\u5b58\u65f6\u5e94\u8fdc\u79bb\u5f3a\u9178\u3001\u6c27\u5316\u5242\uff0c\u907f\u514d\u9ad8\u6e29\u73af\u5883\u3002<\/p>\n<p>\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0cDBU\u5728\u6f6e\u6e7f\u7a7a\u6c14\u4e2d\u4f1a\u7f13\u6162\u5438\u6536\u6c34\u5206\u548cCO\u2082\uff0c\u751f\u6210\u76f8\u5e94\u7684\u8132\u7c7b\u5316\u5408\u7269\uff0c\u5f71\u54cd\u6d3b\u6027\u3002\u56e0\u6b64\uff0c\u5de5\u4e1a\u7ea7DBU\u901a\u5e38\u4ee5\u5bc6\u5c01\u6876\u88c5\u4f9b\u5e94\uff0c\u4f7f\u7528\u524d\u597d\u68c0\u6d4b\u5176\u78b1\u503c\u662f\u5426\u8fbe\u6807\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/27.jpg\" alt=\"\"><\/p>\n<p>\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0cDBU\u5728\u6f6e\u6e7f\u7a7a\u6c14\u4e2d\u4f1a\u7f13\u6162\u5438\u6536\u6c34\u5206\u548cCO\u2082\uff0c\u751f\u6210\u76f8\u5e94\u7684\u8132\u7c7b\u5316\u5408\u7269\uff0c\u5f71\u54cd\u6d3b\u6027\u3002\u56e0\u6b64\uff0c\u5de5\u4e1a\u7ea7DBU\u901a\u5e38\u4ee5\u5bc6\u5c01\u6876\u88c5\u4f9b\u5e94\uff0c\u4f7f\u7528\u524d\u597d\u68c0\u6d4b\u5176\u78b1\u503c\u662f\u5426\u8fbe\u6807\u3002<\/p>\n<h3>\u516d\u3001\u7ecf\u6d4e\u6027\u4e0e\u5e02\u573a\u524d\u666f\uff1a\u8d35\u4e00\u70b9\uff0c\u503c\u4e0d\u503c\uff1f<\/h3>\n<p>\u8bf4\u5b9e\u8bdd\uff0cDBU\u7684\u4ef7\u683c\u6bd4\u4e09\u4e59\u80fa\u8d35\u4e0d\u5c11\u3002\u76ee\u524d\u56fd\u5185\u5e02\u573a\u4ef7\u5927\u7ea6\u572880-120\u5143\/\u516c\u65a4\uff0c\u800c\u4e09\u4e59\u80fa\u53ea\u898120\u5143\u5de6\u53f3\u3002\u4e4d\u4e00\u770b\uff0c\u4f3c\u4e4e\u4e0d\u592a\u5212\u7b97\u3002<\/p>\n<p>\u4f46\u5982\u679c\u6211\u4eec\u7b97\u4e00\u7b14\u201c\u7efc\u5408\u8d26\u201d\uff0c\u7ed3\u8bba\u53ef\u80fd\u5c31\u4e0d\u4e00\u6837\u4e86\uff1a<\/p>\n<ul>\n<li><strong>\u73af\u4fdd\u6210\u672c<\/strong>\uff1a\u4f7f\u7528\u4f4eVOC\u6eb6\u5242\u53ef\u51cf\u5c11\u5e9f\u6c14\u5904\u7406\u6295\u5165\uff0c\u907f\u514d\u73af\u4fdd\u7f5a\u6b3e\uff1b<\/li>\n<li><strong>\u5065\u5eb7\u6210\u672c<\/strong>\uff1a\u964d\u4f4e\u804c\u4e1a\u66b4\u9732\u98ce\u9669\uff0c\u51cf\u5c11\u5458\u5de5\u75c5\u5047\u548c\u8d54\u507f\uff1b<\/li>\n<li><strong>\u4ea7\u54c1\u8d28\u91cf<\/strong>\uff1a\u63d0\u9ad8\u53cd\u5e94\u9009\u62e9\u6027\uff0c\u51cf\u5c11\u6742\u8d28\uff0c\u63d0\u5347\u4ea7\u54c1\u7eaf\u5ea6\uff1b<\/li>\n<li><strong>\u5ba2\u6237\u504f\u597d<\/strong>\uff1a\u8d8a\u6765\u8d8a\u591a\u54c1\u724c\u5546\u8981\u6c42\u4f9b\u5e94\u94fe\u201c\u7eff\u8272\u900f\u660e\u201d\uff0cDBU\u6709\u52a9\u4e8e\u901a\u8fc7\u5ba1\u6838\u3002<\/li>\n<\/ul>\n<p>\u67d0\u56fd\u5185\u5236\u836f\u4f01\u4e1a\u66fe\u505a\u8fc7\u5bf9\u6bd4\u5b9e\u9a8c\uff1a\u5728\u4e00\u6761\u5e74\u4ea750\u5428\u4e2d\u95f4\u4f53\u7684\u4ea7\u7ebf\u4e0a\uff0c\u6539\u7528DBU\u66ff\u4ee3\u4f20\u7edf\u80fa\u7c7b\u540e\uff0c\u867d\u7136\u539f\u6599\u6210\u672c\u4e0a\u5347\u7ea615%\uff0c\u4f46\u56e0\u5e9f\u54c1\u7387\u4e0b\u964d\u3001\u73af\u4fdd\u8bbe\u65bd\u8d1f\u8377\u51cf\u8f7b\u3001\u5458\u5de5\u6ee1\u610f\u5ea6\u63d0\u5347\uff0c\u7efc\u5408\u6548\u76ca\u53cd\u800c\u589e\u52a0\u4e8623%\u3002<\/p>\n<p>\u6240\u4ee5\u8bf4\uff0cDBU\u4e0d\u662f\u201c\u4fbf\u5b9c\u8d27\u201d\uff0c\u4f46\u5b83\u662f\u201c\u806a\u660e\u94b1\u201d\u3002<\/p>\n<h3>\u4e03\u3001\u672a\u6765\u4e4b\u8def\uff1a\u7eff\u8272\u5316\u5b66\u7684\u201c\u7406\u60f3\u578b\u201d<\/h3>\n<p>\u5728\u5168\u7403\u63a8\u52a8\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u5927\u80cc\u666f\u4e0b\uff0c\u7eff\u8272\u5316\u5b66\u516d\u5927\u539f\u5219\u4e4b\u4e00\u5c31\u662f\u201c\u8bbe\u8ba1\u66f4\u5b89\u5168\u7684\u5316\u5b66\u54c1\u201d\u3002DBU\u6070\u597d\u5951\u5408\u8fd9\u4e00\u7406\u5ff5\u2014\u2014\u5b83\u4e0d\u662f\u4fbf\u5b9c\u7684\uff0c\u4e5f\u4e0d\u662f\u5f3a\u529b\u7684\uff0c\u4f46\u5b83\u5728\u6027\u80fd\u3001\u5b89\u5168\u4e0e\u73af\u4fdd\u4e4b\u95f4\u627e\u5230\u4e86\u4f18\u96c5\u7684\u5e73\u8861\u70b9\u3002<\/p>\n<p>\u672a\u6765\uff0c\u968f\u7740\u751f\u7269\u57faDBU\u7684\u5408\u6210\u8def\u5f84\u9010\u6b65\u6210\u719f\uff08\u6bd4\u5982\u5229\u7528\u53ef\u518d\u751f\u539f\u6599\u901a\u8fc7\u50ac\u5316\u73af\u5316\u5236\u5907\uff09\uff0c\u5176\u78b3\u8db3\u8ff9\u5c06\u8fdb\u4e00\u6b65\u964d\u4f4e\u3002\u5df2\u6709\u7814\u7a76\u5c1d\u8bd5\u5c06DBU\u56fa\u5b9a\u5728\u56fa\u4f53\u8f7d\u4f53\u4e0a\uff0c\u5236\u6210\u53ef\u56de\u6536\u50ac\u5316\u5242\uff0c\u5b9e\u73b0\u201c\u7528\u4e00\u6b21\uff0c\u6d17\u4e00\u6d17\uff0c\u8fd8\u80fd\u7528\u201d\u7684\u5faa\u73af\u7ecf\u6d4e\u6a21\u5f0f\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u5728\u65b0\u5174\u9886\u57df\u5982\u53ef\u964d\u89e3\u5851\u6599\u3001\u751f\u7269\u533b\u7528\u6750\u6599\u3001\u67d4\u6027\u7535\u5b50\u5668\u4ef6\u4e2d\uff0cDBU\u7684\u5e94\u7528\u6f5c\u529b\u4ecd\u5728\u4e0d\u65ad\u62d3\u5c55\u3002\u5b83\u6216\u8bb8\u6c38\u8fdc\u4e0d\u4f1a\u6210\u4e3a\u8857\u5934\u5df7\u5c3e\u7684\u70ed\u95e8\u8bdd\u9898\uff0c\u4f46\u5728\u5e55\u540e\uff0c\u5b83\u6b63\u6084\u6084\u652f\u6491\u7740\u4e00\u573a\u9759\u9ed8\u7684\u6280\u672f\u9769\u547d\u3002<\/p>\n<hr \/>\n<h3>\u7ed3\u8bed\uff1a\u4e00\u4e2a\u201c\u5b89\u9759\u7684\u597d\u4eba\u201d\u503c\u5f97\u88ab\u8bb0\u4f4f<\/h3>\n<p>\u5728\u8fd9\u4e2a\u8ffd\u6c42\u901f\u5ea6\u4e0e\u6548\u7387\u7684\u65f6\u4ee3\uff0c\u6211\u4eec\u5e38\u5e38\u5ffd\u7565\u4e86\u90a3\u4e9b\u201c\u4e0d\u5435\u4e0d\u95f9\u201d\u7684\u89d2\u8272\u3002DBU\u5c31\u662f\u8fd9\u6837\u4e00\u4f4d\u5b89\u9759\u7684\u597d\u4eba\u2014\u2014\u5b83\u4e0d\u62a2\u955c\u5934\uff0c\u4e0d\u6563\u53d1\u5f02\u5473\uff0c\u4e0d\u5236\u9020\u9ebb\u70e6\uff0c\u5374\u5728\u65e0\u6570\u5173\u952e\u53cd\u5e94\u4e2d\u9ed8\u9ed8\u53d1\u529b\u3002<\/p>\n<p>\u5b83\u63d0\u9192\u6211\u4eec\uff1a\u771f\u6b63\u7684\u8fdb\u6b65\uff0c\u672a\u5fc5\u6765\u81ea\u8f70\u8f70\u70c8\u70c8\u7684\u53d8\u9769\uff0c\u4e5f\u53ef\u80fd\u6e90\u4e8e\u4e00\u6b21\u6e29\u548c\u7684\u66ff\u4ee3\uff0c\u4e00\u79cd\u514b\u5236\u7684\u9009\u62e9\uff0c\u4e00\u4efd\u5bf9\u73af\u5883\u4e0e\u751f\u547d\u7684\u5c0a\u91cd\u3002<\/p>\n<p>\u6b63\u5982\u7eff\u8272\u5316\u5b66\u4e4b\u7236Paul T. Anastas\u6240\u8bf4\uff1a\u201cDesigning safer chemicals is not an option \u2014 it\u2019s a responsibility.\u201d\uff08\u8bbe\u8ba1\u66f4\u5b89\u5168\u7684\u5316\u5b66\u54c1\u4e0d\u662f\u4e00\u79cd\u9009\u62e9\uff0c\u800c\u662f\u4e00\u79cd\u8d23\u4efb\u3002\uff09<\/p>\n<p>\u800cDBU\uff0c\u6b63\u662f\u8fd9\u4efd\u8d23\u4efb\u4e0b\u7684\u4e00\u4e2a\u6f02\u4eae\u7b54\u6848\u3002<\/p>\n<hr \/>\n<h3>\u4e3b\u8981\u53c2\u8003\u6587\u732e<\/h3>\n<ol>\n<li>\n<p><strong>Anastas, P. T., &amp; Warner, J. C.<\/strong> (1998). <em>Green Chemistry: Theory and Practice<\/em>. Oxford University Press.<br \/>\n\u2014\u2014\u7eff\u8272\u5316\u5b66\u5960\u57fa\u4e4b\u4f5c\uff0c\u63d0\u51fa12\u6761\u57fa\u672c\u539f\u5219\uff0c\u5f3a\u8c03\u5316\u5b66\u54c1\u8bbe\u8ba1\u7684\u5b89\u5168\u6027\u4e0e\u53ef\u6301\u7eed\u6027\u3002\n<\/li>\n<li>\n<p><strong>European Chemicals Agency (ECHA)<\/strong>. (2023). Registered substances: 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU).<br \/>\n<a href=\"https:\/\/echa.europa.eu\">https:\/\/echa.europa.eu<\/a><br \/>\n\u2014\u2014\u6b27\u76df\u5b98\u65b9\u6570\u636e\u5e93\uff0c\u63d0\u4f9bDBU\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u3001\u6bd2\u7406\u5b66\u6570\u636e\u53ca\u76d1\u7ba1\u72b6\u6001\u3002\n<\/li>\n<li>\n<p><strong>United States Environmental Protection Agency (EPA)<\/strong>. (2021). <em>List of Hazardous Air Pollutants<\/em>.<br \/>\n\u2014\u2014\u660e\u786e\u5217\u51fa\u53d7\u63a7VOC\u7269\u8d28\uff0c\u4e3a\u4f4e\u6325\u53d1\u6027\u6eb6\u5242\u7684\u5e94\u7528\u63d0\u4f9b\u653f\u7b56\u4f9d\u636e\u3002\n<\/li>\n<li>\n<p><strong>Zhang, Y., et al.<\/strong> (2020). &quot;DBU-mediated CO\u2082 capture in non-aqueous solvents: Mechanism and regeneration.&quot; <em>Chemical Engineering Journal<\/em>, 389, 124432.<br \/>\n\u2014\u2014\u7cfb\u7edf\u7814\u7a76DBU\u5728\u78b3\u6355\u96c6\u4e2d\u7684\u4f5c\u7528\u673a\u7406\u4e0e\u5faa\u73af\u6027\u80fd\u3002\n<\/li>\n<li>\n<p><strong>Liu, H., &amp; Wang, L.<\/strong> (2019). &quot;Application of DBU in pharmaceutical synthesis: A review.&quot; <em>Chinese Journal of Organic Chemistry<\/em>, 39(6), 1523\u20131534.<br \/>\n\u2014\u2014\u7efc\u8ff0DBU\u5728\u836f\u7269\u5408\u6210\u4e2d\u7684\u5178\u578b\u5e94\u7528\u6848\u4f8b\u4e0e\u4f18\u52bf\u3002\n<\/li>\n<li>\n<p><strong>OECD<\/strong>. (2006). <em>Test No. 201: Freshwater Alga and Cyanobacteria, Growth Inhibition Test<\/em>. OECD Guidelines for the Testing of Chemicals.<br \/>\n\u2014\u2014\u6807\u51c6\u5316\u6c34\u751f\u6bd2\u6027\u6d4b\u8bd5\u65b9\u6cd5\uff0c\u7528\u4e8e\u8bc4\u4f30DBU\u7684\u751f\u6001\u98ce\u9669\u3002\n<\/li>\n<li>\n<p><strong>\u56fd\u5bb6\u5e02\u573a\u76d1\u7763\u7ba1\u7406\u603b\u5c40<\/strong>. (2019). GB 37822-2019\u300a\u6325\u53d1\u6027\u6709\u673a\u7269\u65e0\u7ec4\u7ec7\u6392\u653e\u63a7\u5236\u6807\u51c6\u300b.<br \/>\n\u2014\u2014\u4e2d\u56fd\u73b0\u884cVOC\u6392\u653e\u56fd\u5bb6\u6807\u51c6\uff0c\u6307\u5bfc\u5de5\u4e1a\u5316\u5b66\u54c1\u9009\u578b\u3002\n<\/li>\n<li>\n<p><strong>Smith, M. B., &amp; March, J.<\/strong> (2007). <em>March\u2019s Advanced Organic Chemistry: Reactions, Mechanisms, and Structure<\/em> (6th ed.). Wiley-Interscience.<br \/>\n\u2014\u2014\u7ecf\u5178\u6709\u673a\u5316\u5b66\u6559\u6750\uff0c\u8be6\u7ec6\u89e3\u6790DBU\u7684\u78b1\u6027\u4e0e\u53cd\u5e94\u6d3b\u6027\u3002\n<\/li>\n<li>\n<p><strong>Sheldon, R. A.<\/strong> (2017). &quot;The E-factor: Fifteen years on.&quot; <em>Green Chemistry<\/em>, 19(1), 18\u201343.<br \/>\n\u2014\u2014\u63a2\u8ba8\u7eff\u8272\u5316\u5b66\u8bc4\u4ef7\u6307\u6807\uff0c\u5f3a\u8c03\u51cf\u5c11\u5e9f\u7269\u4e0e\u73af\u5883\u5f71\u54cd\u7684\u91cd\u8981\u6027\u3002\n<\/li>\n<li>\n<p><strong>Chen, J., et al.<\/strong> (2022). &quot;Recyclable DBU-based supported catalysts for esterification reactions.&quot; <em>Catalysis Today<\/em>, 385, 145\u2013152.<br \/>\n\u2014\u2014\u63a2\u7d22DBU\u56fa\u8f7d\u5316\u6280\u672f\uff0c\u63a8\u52a8\u5176\u5728\u53ef\u6301\u7eed\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u3002\n<\/li>\n<\/ol>\n<p>\u8fd9\u4e9b\u6587\u732e\u4ece\u4e0d\u540c\u89d2\u5ea6\u5370\u8bc1\u4e86DBU\u5728\u73b0\u4ee3\u5316\u5b66\u5de5\u4e1a\u4e2d\u7684\u4ef7\u503c\u4e0e\u524d\u666f\u3002\u5b83\u4e0d\u4ec5\u662f\u5b9e\u9a8c\u5ba4\u91cc\u7684\u4e00\u4e2a\u8bd5\u5242\uff0c\u66f4\u662f\u901a\u5411\u7eff\u8272\u672a\u6765\u7684\u6865\u6881\u4e4b\u4e00\u3002<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n<p>===========================================================<\/p>\n<h2>\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n<ul>\n<li>\n<h3>NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-14 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